ISSN:
0887-624X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
High molecular weight alternating block copolymers of polyethesulphone (PES) and polydimethylsiloxane (PDMS) were prepared by the condensation of dimethylamino-terminated PDMS oligomers and hydroxy-terminated PES oligomers in 1,2-dichlorobenzene. Microphase separation of the block copolymers at exceptionally short block lengths was observed by differential scanning calorimetry (DSC) and transmission electron microscopy (TEM). The Si—O—C intersegment linkage in these materials appeared to display poor hydrolytic stability which is contrary to results obtained for other block copolymers.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pola.1991.080290206