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  • 1
    Electronic Resource
    Electronic Resource
    Synthesis of tris(β-diketonato) technetium(III) and its adsorption behaviour on silica gel (1986)
    Springer
    Journal of radioanalytical and nuclear chemistry 103 (1986), S. 19-26 
    Details
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Tris (benzoylacetonato) technetium(III) and tris (2-thenoyltrifluoroacetonato) technetium(III) were synthesized by the direct reduction of pertechnetate with dithionite in the presence of excess ligands. The geometrical isomers of the benzoylacetonate were further separated by means of a silica gel column chromatography. In the silica gel system, the adsorption distribution coefficient of the tris (β-diketonato) technetium(III) decreases in the order of Tc(acac)3〉fac-Tc(bzac)3〉mer-Tc(bzac3)〉Tc(tta)3.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02165360
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