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Complexes of copper(II) with diazabutadienes (1987)

Alvarez-Valdés, Amparo ; Camazón, María José ; Masaguer, José R. ; [et al.]

Springer

Transition metal chemistry 12 (1987), S. 55-58

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ISSN: 1572-901X

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Summary Studies on the chelate complexes of copper(II) with the bidentate ligands, 1,4-diphenyl-2,3-dimethyl-1,4-diazabutadiene (PMB) and 1,4-di(p-methoxyphenyl)-2,3-dimethyl-1,4-diazabutadiene (MPMB), have been carried out. On the basis of the elemental analysis and molar conductivity, the complexes have been characterized as [Cu(PMB)Cl2], [Cu(PMB)2](ClO4)2, [Cu(MPMB)Cl2] and [Cu(MPMB)2](ClO4)2. Both diazabutadienes are bidentate via nitrogen atoms. The temperature dependence of the magnetic susceptibility and the electron paramagnetic resonance, i.r. and u.v.-vis spectra are reported. All compounds appear to be monomers.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01023133

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