ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Treatment oftrans-[Mo(CNMe)2(PMe2Ph)4] andme-[W(CNMe)3(PMe2Ph)3] with sulphuric or hydrochloric acids in methanol or ethanol, or in methanol alone, under irradiation, gives methylamine, ammonia and hydrocarbons (mainly methane). The complex [W2(CNMe)4(μ-CNHMe)2(PMe2Ph)4]2+ cation has been obtained by the treatment ofmer-[W(CNMe)3(PMe2Ph3] with H2SO4 or [Et2OH][BF4] and gives methylamine, ammonia and methane on further acid treatment.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01396938