ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary The isomerization offac-[ReCl(CO)3(PMe2Ph)2]+ to the corresponding meridional-trans isomer has been studied by electroanalytical techniques in MeCN solvent. Chronoamperometric and cyclic voltammetric data relative to the oxidation offac- andmer-[ReCl(CO)3(PMe2Ph)2] allow the accurate determination of the very high kinetic rate constant for the isomerization and permit discussion of thermodynamic aspects of redox homogeneous chemical reactions involving species of the different redox couples arising from the anodic processes.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00626122