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C−H...π(Ar)...H−C host-guest interactions in a novel air-stable cyanoborate clathrate (1994)

Irving, Anne ; Hunter, Roger ; Haueisen, Renate H.

Springer

Journal of chemical crystallography 24 (1994), S. 267-271

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ISSN: 1572-8854

Source: Springer Online Journal Archives 1860-2000

Topics: Geosciences , Physics

Notes: Abstract The host compound forms a coordinato-clathrate in a coordination assisted host lattice. The host lattice is provided by hydrogen bonding between the nitrogen atom of the cyano group and two hydrogen atoms from the phosphonium methyl group. Guest molecules ofp-xylene occupy constricted channels in the lattice. The twop-xylene molecules participate in C−H...π(Ar)...H−C interactions. Results from searches of the Cambridge Structural Database for other C−H...π(Ar)...H−C and C−H...π(Ar) interactions are presented.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01670355

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