ISSN:
1572-8854
Keywords:
Macrocyclic azidotetraamine copper(II) complex
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The complex [Cu(L)N3](H2O)(ClO4) (1) (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,01.18, 07.12]docosane) has been prepared and characterized by X-ray crystallography. 1 crystallizes in the monoclinic space group P21/c, with a = 8.907(5), b = 20.036(3), c = 14.773(2) Å, β = 103.78(2)°, V = 2560.6(15) Å3, and Z = 4. The coordination geometry around the Cu(II) ion is a distorted square-pyramidal with four nitrogen atoms of the macrocycle and one nitrogen atom of the axial azido group.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1022894318159