ISSN:
1572-8862
Keywords:
Ruthenium
;
clusters
;
synthesis
;
electrochemistry
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract The clusters, (μ-H)3Ru3(μ 3-CY)(CO)9−n (PPh3) n [Y=–CH2CHCH2, n=0 (1); Y=–CH2CHCH2, n=3 (2); Y=–C6H4CH3, n=0 (3); Y=–C6H4CH3, n=3 (4)], have been synthesized in good yields and characterized by IR and NMR spectroscopy and by elemental analysis. The electrochemical properties of these clusters is also reported. These data indicate that the π-system of the apical substituent does not interact significantly with the cluster and should be available for further chemistry.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1009001907416
