ISSN:
1572-8986
Schlagwort(e):
Nonthermal plasma
;
CH4
;
N2O
;
NO x
;
CO
;
CO2
;
BaTiO3
;
lattice oxygen
;
atmospheric pressure
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
,
Maschinenbau
,
Technik allgemein
Notizen:
Abstract The behavior of lattice oxygen species of the ferroelectric material during methane oxidation was investigated using a nonthermal plasma reactor packed with BaTiO 3 pellets. Lattice oxygen species in BaTiO 3 play an important role in the formation of N 2 O and the oxidation of CH 4 . The oxidation products such as CO and CO 2 were formed from independent reaction pathways. Lattice oxygen species were able to preferentially oxidize the carbon species deposited on the pellet surface into CO. Also, N 2 O and NO x were independently formed in the N 2–O 2 reaction, suggesting that different oxygen species give N 2 O and NO x. N 2 O was produced by the oxidation of molecular nitrogen with lattice oxygen species.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1023/A:1021897419040
