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  • 1
    Electronic Resource
    Electronic Resource
    Polymerization of benzyl halides catalyzed by VIB metal carbonyls (1983)
    Springer
    Polymer bulletin 9 (1983), S. 349-354 
    Details
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The group VIB metal carbonyls were found to promote the polycondensation of benzyl halides when induced by heat. Their catalytic activity decreases in the order: Mo ≫ W 〉 Cr. Phosphine ligands attached to the metal poison the catalytic activity of the system. Species such as (CO)3M(PhCH 2 + )Cl− are considered to be active in promoting polymerization. The final polybenzyls have a branched, polycondensed structure of moderate molecular weight.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00265312
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