ISSN:
1434-4475
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The reaction of aminofluorsilanes of the type (R=H,F) (Me 3Si)2N−SiF2R with two moles of ammonia, or of a mono- or dialkylamine, yields the corresponding amino-compounds, e.g. (Me 3Si)2N−Si(F)R−NH2, (Me 3Si)2N−Si(F)R−NHR′ and (Me 3Si)2N−Si(F)R−NR2′ (R′=Me, Et). Analogous products are obtained by reaction of the aminofluorosilanes with lithium salts of amines with bulky organic substituents in a 1 : 1 molar ratio. Alkoxy- and aryloxyaminofluorosilanes are prepared by the reaction of sodium alcoholates and sodium phenolate with (Me 3Si)2N−Si(F2)R (R=H, C2H3, C2H5, C6H5). The i.r.-, mass-,1H- and19F-NMR spectra of the above compounds are reported.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01150527
