ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
In the title compound, [Zn(CH5N3S)2](NO3)2, the zinc(II) ion is located on the twofold axis and chelated by two thiosemicarbazide ligands with Zn—S and Zn—N distances of 2.0904 (17) and 2.2672 (6) Å, respectively. Thus the central zinc(II) is four-coordinated and in a distorted tetrahedral geometry. The inter- and intramolecular hydrogen bonds formed between thiosemicarbazide ligands and nitrate anions assemble the molecules into a one-dimensional chain.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270199012974