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Digitale Medien

Diiodobis(1-methyl-1,3-imidazolium-2-thiolato-S)mercury(II) (2000)

Pavlovic, Gordana ; Popovic, Zora ; Soldin, Zeljka ; [weitere]

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 56 (2000), S. 801-803

zur Merkliste hinzufügen auf der Merkliste

Details

ISSN: 1600-5759

Quelle: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Thema: Chemie und Pharmazie , Geologie und Paläontologie , Physik

Notizen: The reaction of 1-methyl-1,3-imidazole-2-thione (meimtH) with mercury(II) iodide in methanol in a 2:1 molar ratio resulted in the formation of single crystals of the title compound, [HgI2(C4H6N2S)2]. The Hg atom is coordinated by two I [2.7809 (9) and 2.7999 (8) Å] and two thione S atoms [2.520 (3) and 2.576 (3) Å] with irregular tetrahedral coordination geometry. The NH groups of the imidazole ring take part in intra- and intermolecular hydrogen bonds with I atoms [N...I 3.596 (8) and 3.611 (9) Å, respectively] joining molecules into infinite chains parallel to the z axis.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1107/S0108270100005825

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