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catena-Poly[[silver(I)-μ-[(E)-1,2-bis(2-pyridyl)ethylene-N:N′]] nitrate] (2000)

Tong, Ming Liang ; Chen, Xiao Ming

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 56 (2000), S. 1075-1076

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ISSN: 1600-5759

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: In the title complex, {[Ag(C12H10N2)]NO3}n, the Ag atom, which is in a linear AgN2 geometry, is surrounded by two trans-related N atoms of two bpe ligands [Ag—N = 2.173 (3) and 2.176 (3) Å; bpe is trans-1,2-bis(2-pyridyl)ethylene]. The bpe ligands bridge neighbouring Ag atoms to form zigzag polymeric chains in the lattice. These adjacent one-dimensional zigzag chains are extended into a three-dimensional supramolecular array by strong interchain π...π interactions between the pyridyl rings of adjacent chains.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0108270100008647

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