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catena-Poly[[bis(nitrato)(pyrimidine)copper(II)]-μ-pyrimidine-N:N′] (2000)

Riggio, Ivonne ; Albada, Gerard A. van ; Mutikainen, Ilpo ; [et al.]

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 56 (2000), S. e380-e381

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ISSN: 1600-5759

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: The title compound, [Cu(NO3)2(C4H4N2)2]n, crystallizes as a linear polymeric compound with one pyrimidine ligand bridging between two CuII atoms and a second pyrimidine ligand coordinated in a monodentate manner. The distorted octahedral geometry around the CuII atom consists of two pyrimidine N atoms at distances of 2.033 (4) and 2.025 (4) Å, and two nitrate O atoms at distances at 1.987 (3) and 1.973 (3) Å. The apical positions are occupied by an N atom of a bridging pyrimidine ligand [2.291 (4) Å] and a nitrate O atom at a long distance of 2.781 (3) Å. The basal plane is almost planar, with trans angles of 176.23 (14) and 165.34 (15)°.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S010827010001101X

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