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Potassium thiocyanate argentates: K3[Ag(SCN)4], K4[Ag2(SCN)6] and K[Ag(SCN)2] (2001)

Krautscheid, Harald ; Gerber, Stefan

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 57 (2001), S. 781-783

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ISSN: 1600-5759

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: The anions of the title compounds contain [Ag(SCN)4] units, with the S atoms coordinating to Ag+ in a tetrahedral arrangement. Whereas in the isolated anions of tripotassium tetrathiocyanatoargentate(I), K3[Ag(SCN)4], (I), all SCN− groups are bonded as terminal ligands, in tetrapotassium di-μ-thiocyanato-S:S-bis[dithiocyanatoargentate(I)], K4[Ag2(SCN)6], (II), two AgS4 tetrahedra share one common edge. In poly[potassium [argentate(I)-di-μ-thiocyanato-S:S]], K[Ag(SCN)2], (III), edge- and vertex-sharing of AgS4 tetrahedra results in infinite [Ag(SCN)2]− layers.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0108270101005650

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