ZIB

Hits per page

hit 1 - 1 | 1 hit

Select All Export

Electronic Resource

Chloro(propionyl-C)[2(1H)-pyridonato-N,O]bis[tris(1-methylethyl)phosphine]iridium(III) (1996)

Grotjahn, D. B. ; Lo, H. C. ; Groy, T. L.

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 52 (1996), S. 516-519

add to mindlist on the mindlist

Details

ISSN: 1600-5759

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: The title compound, [IrCl(C3H5O)(C5H4NO){(C3H7)3P}2], is a mononuclear complex of a chelated 2(1H)-pyridinone anion, exhibiting a slightly distorted octahedral geometry. The monohapto carbon-bound propionyl ligand and the O atom of the dihapto pyridinonato ligand are mutually trans, and the phosphine ligands tilt away from the propionyl ligand towards the O atom of the heterocyclic ligand. The Ir—O bond length is unusually long for a complex of 2(1H)-pyridinone, a circumstance attributed to the strong trans influence of the acyl ligand.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0108270195010997

Library	Location	Call Number	Volume/Issue/Year	Availability

Others were also interested in ...

Paper (German National Licenses)

Fulltext

hit 1 - 1 | 1 hit