Electronic Resource
Woodbury, NY
:
American Institute of Physics (AIP)
Applied Physics Letters
62 (1993), S. 3028-3030
ISSN:
1077-3118
Source:
AIP Digital Archive
Topics:
Physics
Notes:
The evolution of phases leading to the formation of epitaxial films of nominal composition Tl2Ba2CaCu2O8 on (100) LaAlO3 by post-deposition annealing of amorphous precursor films has been investigated by examining interrupted heat-treatment samples using analytical microscopy and x-ray diffraction. The superconductor, with a composition of Tl1.8Ba2Ca0.94Cu2.6Ox, forms from a melt, which itself formed from intermediary crystalline phases during the continual loss of Tl2O. It is concluded that Tl1.8Ba2Ca0.94Cu2.6Ox, Cu2O, and Tl3Ca5Ox are in subsolidus equilibrium and that a melt phase exists between at least 780 and 860 °C under reducing conditions controlled by the Tl2O vapor.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.109149
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