ZIB

Hits per page

hit 1 - 1 | 1 hit

Select All Export

Electronic Resource

The electrical double layer in wall–wall hypernetted chain approximation with bridge functions (1993)

Attard, Phil ; Miklavic, S. J.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 99 (1993), S. 6078-6086

add to mindlist on the mindlist

Details

ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The wall–wall Ornstein–Zernike equation is formulated for the case of charged walls in a primitive model electrolyte. Numerical results are presented for the modified hypernetted chain (HNC) closure, which includes the effects of ion size and correlations. The bare HNC gives attractions between like-charged surfaces rather too readily, but this is ameliorated by the inclusion of the first bridge diagram. The singlet approach is shown to be accurate in divalent electrolyte, and in the large separation asymptotic regime. The method is less reliable in dilute monovalent electrolyte.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.465905

Library	Location	Call Number	Volume/Issue/Year	Availability

Others were also interested in ...

Paper (German National Licenses)

Fulltext

hit 1 - 1 | 1 hit