Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
94 (1991), S. 5855-5864
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The NaLi 1 1Σ+(X) electronic ground state has been studied by Fourier transform spectroscopy and laser-induced fluorescence up to near the dissociation limit. The fluorescence has been induced by Ar+, Kr+ and dye (DCM and rhodamine 6G) laser lines. Fluorescence spectra have been observed up to v‘=43 and accurate molecular constants have been calculated for the electronic ground state after reducing the wave numbers of 6417 assigned lines in a least-squares fit. With the molecular constants an inverted-perturbation-approach potential curve has been calculated. A value for the dissociation energy of De=7105.5±1.0 cm−1 has been obtained by fitting the energy levels with high vibrational quantum numbers to a multipolar expansion in the inverse power of the internuclear distance. The multipolar expansion coefficients C6, C8, and C10 have been obtained, showing a good agreement with theoretical values calculated earlier. In the fluorescence spectrum induced by the 476.5 nm Ar+ laser line, extra fluorescence series have been observed. The possible collisional energy transfer in the 1 1Π(B) electronic state at the origin of these lines is discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.460469
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