ZIB

Hits per page

hit 1 - 1 | 1 hit

Select All Export

Electronic Resource

Subpicosecond predissociation dynamics of the methyl radical Rydberg 3 s state (1991)

Westre, S. G. ; Kelly, P. B. ; Zhang, Y. P. ; [et al.]

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 94 (1991), S. 270-276

add to mindlist on the mindlist

Details

ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The subpicosecond dissociation dynamics of the methyl radical 3 s Rydberg state have been examined using rotational resonance Raman spectroscopy. The rovibronic dependence of the excited state predissociation rates and lifetimes are obtained for the B˜ state origin vibrational level of CH3 and CD3. Analysis of the tunneling rates using a cubic potential barrier yields estimates for the height (2200 cm−1) and position of the barrier along the dissociation coordinate (1.38 A(ring)). A comparison of the potential energy surface parameters for the Rydberg 3 s states of methyl radical and ammonia is presented.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.460394

Library	Location	Call Number	Volume/Issue/Year	Availability

Others were also interested in ...

Paper (German National Licenses)

Fulltext

hit 1 - 1 | 1 hit