Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
93 (1990), S. 2370-2374
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Experimental data on the positions and widths of the vibrational energy levels of the C 3Πg Rydberg state of molecular oxygen are interpreted. The energy levels are described as resonances in the elastic scattering of oxygen atoms in the open 1 3Πg valence state caused by a coupling to the closed C 3Πg Rydberg state. The coupled scattering equations are set up with an empirical valence potential energy curve and Rydberg-valence interaction potential and it is shown that the energy level positions and widths can be reproduced by an interaction of 63 meV and a potential energy curve that crosses the Rydberg curve on the attractive part of its outer limb.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.459017
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