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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 6794-6799 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The heat capacity of the perovskite high-TC superconductor YBa2Cu3O7−δ was measured from 5.3 to 350 K in an adiabatic calorimetric cryostat. A break in the heat-capacity curve, associated with the critical temperature for superconductivity was observed between 90.09 and 92.59 K. The transition temperature was identified as 91.44 K, and ΔCp,m was calculated to be 0.559R at that temperature. The lattice heat capacity was evaluated by means of the recently developed Komada/Westrum phonon distribution model and the apparent characteristic temperature aitch-thetaKW was calculated to be 107.7 K. The excess electronic heat capacity for the superconducting phase was evaluated and the energy gap was identified as 234. R K. Excess contribution, resulting from magnetic impurities, was noted below 20 K. Thermodynamic properties at selected temperatures are presented.
    Type of Medium: Electronic Resource
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