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Chemical equilibrium in argon: Anomaly of density dependence of dimerization reaction in the medium density region (1989)

Kimura, Y. ; Yoshimura, Y. ; Nakahara, M.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 91 (1989), S. 2758-2759

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: We studied the dimerization equilibrium of 2-methyl-2-nitrosopropane in argon at 25.0 °C from about 500 to 1200 kg m−3. It is clarified that in the simplest solvent, argon, there exists a definite difference in the density dependence of the equilibrium constant between the high and medium density regions. In the high density region, the equilibrium constant shows a sizable increase with the solvent density as in the liquid phase. Near the critical density, however, the equilibrium constant shows little density dependence.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.456991

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