ZIB

Hits per page

hit 1 - 1 | 1 hit

Select All Export

Electronic Resource

Vibrational relaxation and electronic quenching rate coefficients for BiF(A0+,v') by SF6 (1988)

Helvajian, H. ; Holloway, J. S. ; Koffend, J. B.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 89 (1988), S. 4450-4451

add to mindlist on the mindlist

Details

ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: We have extended our kinetic data base for the A state of BiF to include SF6 as a collision partner. By applying a four level finite difference fitting routine to time-resolved fluorescence traces from v'=0–3, we have obtained rate coefficients for electronic quenching, and for vibrational relaxation within the A-state manifold. As was the case for our previous results in He and Ar, electronic quenching is slow in comparison to radiative decay. Vibrational relaxation does not show a simple v' dependence, but rather, for the levels examined, increases markedly for higher v'. Our results confirm the suitability of SF6 as a bulk diluent in the proposed NF/BiF chemical laser system.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.455701

Library	Location	Call Number	Volume/Issue/Year	Availability

Others were also interested in ...

Paper (German National Licenses)

Fulltext

hit 1 - 1 | 1 hit