Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
89 (1988), S. 51-54
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The depolarization of the totally symmetric (ν1) Raman band of liquid carbon tetrachloride has been measured at 22 °C and pressures up to the freezing pressure of 1.1 kbar using the scattering geometry Z(YZ)Y, which causes little depolarization by the windows. The depolarization decreases linearly from 6.5×10−3 at zero pressure to 5.6×10−3 at 1.15 kbar. The change is explained as the resultant of a decrease of both the vibrational amplitude and the mean intermolecular distance under pressure.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.455495
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