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Large paramagnetic anisotropy of NaMg[Cr(oxalate)3]⋅9H2O (1987)

Merabet, K. E. ; Carlin, Richard L.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 87 (1987), S. 1546-1548

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The magnetic susceptibilities of single crystals of NaMg[Cr(oxalate)3]⋅9H2O are reported over the temperature interval 40 mK–4.2 K. Large anisotropy is observed due to the large zero-field splitting of the 4A2 ground state; the parameters that fit the data are 2D/k =−2.45(3) K, g(parallel)=1.985(5), g⊥=2.035(10), and an exchange correction of zJ/k =0.006(1) K.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.453266

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