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Size of a polyelectrolyte chain in solution containing counterions (1987)

Chen, Y. ; Kholodenko, A. L.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 86 (1987), S. 1540-1541

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: Using the method of Edwards and Singh we calculate the mean square radius 〈R2〉 of the polyelectrolyte chain in solution containing counterions for the temperature greater than the Flory's θ temperature. For the counterion density n we obtain: (a) 〈R2〉∝L2 when n→0, and (b) 〈R2〉∝L6/5 when n→∞. These results are in agreement with the Flory-type calculations and recent Monte Carlo simulations performed by Baumgärtner.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.452191

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