Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
111 (1999), S. 3183-3191
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The critical properties of binary mixtures of linear and branched alkanes have been evaluated using perturbation theory. An accurate equation of state for the reference system is combined with a mean field treatment of the perturbation term, along with a reasonable potential model. No adjustable parameters were used either for the pure compounds or for the binary mixtures. The aim of this work is to show which features of the critical properties of alkane mixtures can be obtained from a fully molecular based theory. It is shown that the main trends of the critical properties of alkane binary mixtures can be described qualitatively by the theory. © 1999 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.479598
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