ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
A lattice gas model with nonadditive lateral interactions is used to describe Ag, Au and AgAu bilayer films on a Ru(0001) substrate. By Monte Carlo simulations of adsorbate configurations and thermal desorption spectra of the Ag, Au and AgAu films, the microscopic interaction parameters of the gold and silver adatoms in the alloy film on Ru(0001) are obtained. The model reproduces experimental thermal desorption spectra of Ag, Au and AgAu films on Ru(0001) and also shows segregation of silver in the second monolayer of the alloy in agreement with experimental results. Based on perturbation theory, the configurational Gibbs free energy G of the AgAu monolayer alloy is calculated as a function of temperature and composition. © 1998 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.475824
