Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
101 (1994), S. 7273-7282
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
A new NMR spectroscopic method is described that allows a selective determination to be made of whether two sites are connected by a slow conformational exchange process. An accompanying approximate theory is derived which permits a quantitative estimate to be made of the exchange rate in numerous situations. Numerical simulations are presented to specify the domain of validity of the theory. Experimental verification is demonstrated for an aromatic ring in the bovine pancreatic trypsin inhibitor protein.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.468284
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