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State selective production of phosphorus ions via multiphoton ionization of atomic phosphorus (1994)

Harbol, M. R. ; Appling, J. R. ; Goren, A. C.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 101 (1994), S. 2659-2664

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The (2+1) resonance-enhanced multiphoton ionization spectrum of phosphorus atoms is reported for the wavelength range 300–317 nm. Atomic phosphorus is formed by multiphoton photodissociation of phosphorus tribromide vapor. Photoelectron spectroscopy conducted at phosphorus ionization resonances produces pure populations of P+(3PJ) and P+(1D2) ions. Production of a mixture of phosphorus ionic states indicates a clear propensity to preserve the ion core electron configuration upon ionization of phosphorus. Four spin-changing transitions are assigned supported by photoelectron spectral data.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.467645

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