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TixZryC12 and TixHfyC12 (x+y=8): Binary metal metallocarbohedrenes (1994)

Cartier, S. F. ; May, B. D. ; Castleman, A. W.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 100 (1994), S. 5384-5386

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: We report the production of binary metal metallocarbohedrenes. Direct laser vaporization of mixtures of zirconium or hafnium powders with titanium carbide yield the species TixZryC12 and TixHfyC12 (x+y=8). These results are discussed in the context of recent theoretical models addressing the stabilities and structures of the metallocarbohedrenes, their formation mechanism and possible implications for the synthesis of "doped'' metallocarbohedrenes.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.467154

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