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New Routes to Tetrahalomethanes (1957)

HASZELDINE, R. N. ; ISERSON, H.

[s.l.] : Nature Publishing Group

Nature 179 (1957), S. 1361-1362

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ISSN: 1476-4687

Source: Nature Archives 1869 - 2009

Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics

Notes: [Auszug] Reaction of phosgene with phosphorus penta-chloride at 350 C. under pressure yields carbon tetrachloride in 60-70 per cent conversion. Carbonyl fluoride similarly gives dichlorodifiuoromethane between 100 and 400 C, though in much lower yield : COX2 + PC16 -* CX2C12 + POC13 ; X = F or Cl ...

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1038/1791361b0

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