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Electrosynthesis of ammonia (1985)

Pickett, Christopher J. ; Talarmin, Jean

[s.l.] : Nature Publishing Group

Nature 317 (1985), S. 652-653

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ISSN: 1476-4687

Source: Nature Archives 1869 - 2009

Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics

Notes: [Auszug] The dinitrogen complex frans-[W(N2)2 (Ph2PCH2CH2PPh2)2] reacts with tosylic acid p-CH3C6H4SO3H · H2O, TsOH · H2O, in tetrahydrofuran (thf) to give the hydrazido(2-)-cation, trans-[W(NNH2)TsO(Ph2PCH2CH2PPh2)2]+(A) (see scheme I, reaction (i) in Pig. 1). The cation, A, was isolated and characterized ...

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1038/317652a0

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