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  • Articles: DFG German National Licenses  (2)
  • 71.55.Jv  (1)
  • STM  (1)
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  • Articles: DFG German National Licenses  (2)
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  • 1
    ISSN: 1572-879X
    Keywords: active sites ; surface alloys ; STM ; molecular beams ; activation barriers
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract This report describes a combined experimental and theoretical approach to the problem of designing surface alloys with specific chemical properties. Au-Ni(111) surface alloys were prepared and the distribution of active sites was determined by atomically resolved STM as a function of Au coverage. Using density functional theory the difference in activation energy for methane over the various sites was determined. The activity of the surface could be predicted directly by combining this information with the distribution of sites. Subsequent measurements of the activity proved this method to be quantitative and demonstrated that surface alloys with specific activity can be synthesized.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 94 (1994), S. 147-153 
    ISSN: 1434-6036
    Keywords: 73.40.Hm ; 05.40.+j ; 71.55.Jv
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Velocity correlation functions in the time domain offer a new approach to the dissipative conductivity in the quantum Hall effect at half-filled Landau bands. We describe two methods of calculating these functions directly by wave packet propagation techniques. We address the question whether quantum effects modify the high field diffusion described within the semiclassical percolation picture of the QHE. We investigate a number of random potentials with finite correlation length. Coupling to higher Landau levels leads to damped cyclotron oscillations in the velocity correlation. Besides that, we observe a long time tail Φ(t)∼t −κ with κ≈2.3 for all potential ranges investigated. Within the statistical uncertainty and the time interval considered, this power law is consistent with the semiclassical result obtained by averaging over all cluster sizes. Our findings imply detectable deviations from Drude's law for the AC conductivity.
    Type of Medium: Electronic Resource
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