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  • Articles: DFG German National Licenses  (4)
  • Organic Chemistry  (3)
  • Alpine foreland  (1)
  • 1
    ISSN: 1617-6278
    Keywords: Eemian interglacial ; Late Pleistocene ; Altitudinal zonation ; Pollen analysis ; Alpine foreland
    Source: Springer Online Journal Archives 1860-2000
    Topics: Archaeology , Biology
    Notes: Abstract Pollen analytical data from a 23-m core taken in the Jammertal subglacial basin, near Biberach an der Riss, has given a continuous sequence from the Rissian late-glacial to the beginning of the Mid-Würmian. The Eemian interglacial is completely preserved and with a high temporal resolution. Two interstadials, Stafflangen I and II, are recognised in the Lower Würmian. These two woodlands were dominant byPinus andPicea and there was a small but significant (up to 12%) component of thermophilous deciduous tree pollen. Stafflangen I and II are correlated with St. Germain I and II as known from Grande Pile. The north-eastern areal boundary of thermophilous deciduous trees lies between Jammertal and Grande Pile. Furthermore, it was possible for the first time to define and describe altitudinal zonation in Eemian vegetation. During the Eemian, the altitudinal boundary of shade-tolerant deciduous trees (Carpinus, Abies andPicea) lay at ca. 625 m in Upper Swabia and the Swiss Alpine foreland, and at ca. 560 m in Upper Bavaria to the east. The sites, which were dominated byCarpinus occur below this limit whereasAbies orPicea show a preference for habitats at higher altitudes.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 77 (1994), S. 1611-1615 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Formation, X-Ray Crystal Structure, and Absolute Configuration of (-)-N-(Chloromethyl)galanthaminium ChlorideThe acetylcholinesterase inhibitor galanthamine (1), main alkaloid of several Narcissus species, readily forms a quaternary ammonium salt by reaction with the solvent CH2Cl2. The structure and absolute configuration of (-)-N-(chloromethyl)galanthaminium chloride (2) were determined by X-ray diffraction (R = 0.075 for 2775 observed independent reflexions) and NMR spectroscopy. The tetragonal crystals (space group P43) contain two crystallographically independent cations which do not differ significantly from one another. The CH2Cl group is attached to the quaternary N-atom in stereospecific (R)-configuration. In the crystal, the configurational position of the Me group at the N-atom of 2 differs from that of the crystalline free base 1. Hydrogen bonding is observed from the OH group at C(3) of 2 to the Cl- anion or to the Cl-atom of an adjacent cation.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1984 (1984), S. 306-318 
    ISSN: 0170-2041
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Intramoleclar Addition of Carbanions to AnthraquinonesThe intramolecular Michael addition of the carbanions derived from the β-keto diesters 15a and 15b yields the naphthacenequinones 20a and 20b. In contrast, the similar dimethyl ether 11 cyclizes to give the benzo[α]anthracenequinone 17. The hydroquinone of 1,8-dihydroxyanthraquinone (5a) reacts with acrylate to yield the unusual anthrone derivatives 12b and 12c.
    Notes: Die intramolekulare Michael-Addition der Carbanionen, die sich von den β-Ketodiestern 15a und 15b ableiten, liefert die Naphthacenchinone 20a und 20b. Dagegen cyclisiert der Dimethylether 11 zum Benzo[α]anthracenchinon 17. Das Hydrochinon des 1,8-Dihydroxyanthrachinons (5a) reagiert mit Acrylsäureester zu den ungewöhnlichen Anthron-Derivaten 12b und 12c.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Einwirkung von Perjodat auf Dextran, Xylan, Inulin und Saccharose führt zu Oxydationsprodukten dieser Zucker, die mit Phenylhydrazin unter anderem Abkömmlinge der Rubazonsäure ergeben.  -  Die gleichen Verbindungen entstehen bei Einwirkung von asymmetrisch disubstituierten Arylhydrazinen auf D-Fructoson-1-phenylhydrazon oder auf Glycerose-phenylosazon und durch Umsetzung von Glycerinaldehyd-methylphenylhydrazon mit Phenylhydrazin. Es wird über Synthese und Eigenschaften dieser Verbindungen berichtet.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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