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  • Articles: DFG German National Licenses  (15)
  • Polymer and Materials Science  (11)
  • Cotransport  (2)
  • Electron microscopy  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Biochimica et Biophysica Acta (BBA)/Biomembranes 731 (1983), S. 437-447 
    ISSN: 0005-2736
    Keywords: (Rabbit small intestine) ; Amino group ; Chemical modification ; Cotransport ; Glucose transport ; Na^+ transport ; Phlorizin binding ; Substrate-binding site
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Medicine , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Biochimica et Biophysica Acta (BBA)/Biomembranes 728 (1983), S. 429-437 
    ISSN: 0005-2736
    Keywords: (Rabbit brush border) ; Amino group ; Chemical modification ; Cotransport ; Na^+/glucose transport ; Phlorizin binding ; Sulfhydryl group
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Medicine , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Biochimica et Biophysica Acta (BBA)/Gene Structure and Expression 696 (1982), S. 76-86 
    ISSN: 0167-4781
    Keywords: (Adenovirus) ; Chromatin ; Electron microscopy ; Nuclease digestion
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Medicine , Physics
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1432-072X
    Keywords: Bradyrhizobium ; Electron microscopy ; Mutants ; Nitrogen fixation ; Nodulation ; Soybean ; Symbiosis ; Transposon Tn5
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The genome of the slow-growing Bradyrhizobium japonicum (strain 110) was mutagenized with transposon Tn5. A total of 1623 kanamycin/streptomycin resistant derivatives were screened in soybean infection tests for nodulation (Nod) and symbiotic nitrogen fixation (Fix). In this report we describe 14 strains possessing a stable, reproducible Nod+Fix- phenotype. These strains were also grown under microaerobic culture conditions to test them for free-living nitrogen fixation activity (Nif). In addition to strains having reduced Fix and Nif activities, there were also strains that had reduced symbiotic Fix activity but were Nif+ ex planta. Analysis of the genomic structure revealed that the majority of the strains had a single Tn5 insertion without any further apparent physical alteration. A few strains had additional insertions (by Tn5 or IS50), or a deletion, or had cointegrated part of the vector used for Tn5 mutagenesis. One of the insertions was found in a known nif gene (nifD) whereas all other mutations seem to affect different, hitherto unknown genes or operons. Several mutant strains had an altered nodulation phenotype, inducing numerous, small, widely distributed nodules. Light and electron microscopy revealed that most of these mutants were defective in different stages of bacteroid development and/or bacteroid persistence. The protein patterns of the mutants were inspected by two-dimensional gel electrophoresis after labelling microaerobic cultures with l-(35S)methionine. Of particular interest were mutants lacking a group of proteins the synthesis of which was known to be under oxygen control. Such strains can be regarded as potential regulatory mutants.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 11 (1980), S. 244-258 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Behaviour of stainless cast alloys under combined mechanical and corrosive attackIn media with 3000 mg B/1 (as boric acid, H3BO3) and varying chloride contents down to 1 mg Cl-/1 13%-Cr-steels show pitting. Under constant load cracks appear simultaneously. As can be expected, 17%-Cr-steels are more resistant and duplex ferritic austenitic steels exhibit no corrosion cracking in 3% NaCl-solution even after 10 000 hrs. Generally, corrosion resistance improves with increasing contents of ferrite forming elements. Corrosion cracks are interpreted in termes of anodic stress corrosion cracking. Notch impact bending tests with hydrogen charged specimens show that deformability is reduced.
    Notes: 13%-Cr-Stähle zeigen in Lösungen mit 3000 mg B/1 (als Borsäure, H3BO3) und unterschiedlichen Chloridgehalten Lochkorrosion bis herab zu Konzentrationen von 1 mg Cl-/1. Bei mechanischer Zugbeanspruchung treten gleichzeitig Risse auf. 17%-Cr-Stähle sind erwartungsgemäß beständiger und ferritisch-austenitische Stähle zeigen in 3% NaCl-Lösung auch im 10 000 h-Versuch keine Korrosionsrisse. Generell steigt die Beständigkeit mit zunehmendem Anteil an ferritbildenden Elementen. Die Korrosionsrisse werden als anodische Spannungsrißkorrosion interpretiert. Kerbschlagbiegeversuche mit wasserstoffbeladenen Proben ergeben eine Abnahme des Verformungsvermögens.
    Additional Material: 21 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 26 (1975), S. 192-199 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The inhibition of cooling systemsThe choice of an efficient corrosion inhibitor has to take in account the type of the cooling system, the materials used as well as the specific operating conditions, for instance - very low or very high velocities of the cooling water- heat transfer- the inhibitor may be asked to have some lubricating properties- vibrations, that can cause cavitation or fatigue corrosion- interaction between the corrosion inhibitor and other electrochemical systems of corrosion protection (cathodic protection).In numerous applications it is necessary to improve the inhibition by an addition of other effective substances (like dispersants, hardness stabilizers, mixture of inhibitors with selective protection properties).
    Notes: Die Auswahl eines Kühlwasserinhibitors richtet sich nach der Art des Kühlsystems und der darin verwendeten Werkstoffe sowie nach den spezifischen Beanspruchungen, so z. B.- extrem hohe oder niedrige Strömungsgeschwindigkeiten des Kühlmediums,- hohe Wärmebelastung der zu Kühlenden Metallwand,- Reibungsvorgänge, wobei der Inhibitor zusätzlich eine Schmierfunktion ausüben muß,- Vibrationen, die zu Kavitationserscheinungen oder zur Werkstoffermüdung führen Können,- Wechselwirkungen des Inhibitors mit anderen elektrochemischen Schutzverfahren (z. B. lokaler kathodischer Schutz von hochbeanspruchten Zonen des Kühlsystems).In zahlreichen Fällen ist es zudem notwendig, die Wirksamkeit der Inhibierung durch den Zusatz von weiteren Wirkstoffen zu unterstützen (Dispergiermittel, Härtestabilisatoren, Gemische von Inhibitoren mit selektiver Schutzwirkung).
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 27 (1976), S. 425-431 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Testing and Selecting Cavitation InhibitorsAn investigation has been made into possibility of using electrochemical procedures as well as the gravimetrical method for testing cavitation inhibitors. The relation between the structure of the inhibitor, the nature and form of the cavitation attack and the mechanism of destruction was also examined. This work was performed with a group of conventional cooling water inhibitors and some pyridine compounds.It was shown that electrochemical investigations are less suitable for enabling inhibitors to be selected for high cavitation intensities, because electrochemical losses amount to only a relatively small part of the total loss of material. Nevertheless they are indispensable as a supplement to magnetostrictive investigations for appraising the overall performance of an inhibitor, because it has been found that a good cavitation inhibitor does not always achieve the same success against electrochemical corrosion.Furthermore it was demonstrated that interface inhibitors generally yield better results than membrane inhibitors or passivators. The protection afforded by interface inhibitors depends on their structure, the chain length and in the case of the pyridine components investigated the nature and position of the substituents in the pyridine ring.
    Notes: Es wurde untersucht, ob für die Erprobung von Kavitationsinhibitoren neben der gravimetrischen Methode auch elektrochemische Prüfverfahren eingesetzt werden können. Es wurde ferner der Zusammenhang zwischen Struktur des Inhibitors, Art und Form des Kavitationsangriffes und Mechanismus der Zerstörung untersucht. Diese Arbeit wurde mit einer Gruppe herkömmlicher Kühlwasserinhibitoren sowie mit einigen Pyridinverbindungen durchgeführt.Wie es sich zeigte, sind elektrochemische Untersuchungen weniger geeignet, eine Inhibitorauswahl bei hohen Kavitationsintensitäten zu ermöglichen, da die elektrochemische Metallauflösung nur einen relativ kleinen Teil des gesamten Abtrags ausmacht. Sie sind aber als Ergänzung zu magnetostriktiven Untersuchungen für die Beurteilung des Gesamtverhaltens eines Inhibitors unbedingt notwendig, da es sich gezeigt hat, daß nicht immer ein guter Kavitationsinhibitor mit demselben Erfolg gegen elektrochemische Korrosion eingesetzt werden kann.Wie sich außerdem herausstellte, liefern Grenzflächeninhibitoren in der Norm bessere Resultate als Membraneninhibitoren oder Passivinhibitoren. Bei den Grenzflächeninhibitoren ist die Schutzwirkung von der Struktur des Inhibitors abhängig, wobei insbesondere Kettenlänge und - bei den untersuchten Pyridinverbindungen - Art und Stellung der Substituenten eine wichtige Rolle spielen.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 25 (1974), S. 734-739 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The influence of imposed protection currents on the efficiency of inhibitors for cooling watersIn case where the cathodic protection of a cooling system is not feasible a combination of cathodic protection and inhibition may be of advantage. The authors have studied the potential influence of a direct current on the efficiency of an inhibitor; during the experimental work they have used a current intensity corresponding to the maximum intensity of the protection current used in practice. Using potentiokinetic methods they have found that the number of inhibitors which may be used in such conditions is rather small. In the case of inhibitors based on nitrites or amines the protecting efficiency is rather reduced after some hundred hours' operation under direct current, and in some case even a corrosion stimulation has been experienced. Inhibitors based on chromates and anticorrosion oil emulsions exhibit improved electrochemical stability, though, in the case of oils emulsion breaking must be taken into account after relatively short durations of operation.
    Notes: In Fällen, wo der kathodische Schutz eines Kühlsystems schwer durchführbar ist, erweist sich eine Kombination von kathodischem Schutz und Inhibierung als vorteilhaft. Die Verfasser untersuchten mögliche Einflüsse von Gleichstrom auf die Wirksamkeit von Inhibitoren; bei diesen Versuchen arbeiteten sie mit einer Stromstärke, welche der maximalen in der Praxis verwendeten Schutzstromstärke entsprach. Mit Hilfe von potentiokinetischen Methoden wurde gefunden, daß die zahl der unter diesen Bedingungen verwendbaren Inhibitoren sehr klein ist. Im Falle von Inhibitoren auf Basis von Nitriten oder Aminen verringert sich schon nach einigen Stunden Gleichstromeinwirkung die Schutzwirkung und in manchen Fällen zeigt sich sogar eine stimulierende Wirkung. Die Inhibitoren auf Basis von Chromaten oder Korrosionsschutzölemulsionen sind hingegen elektrochemisch gut beständig im Falle der Öle ist jedoch damit zu rechnen, daß die Emulsion schon nach verhältnismäßig kurzer Betriebsdauer bricht.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 19 (1968), S. 895-900 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Pitting and contact corrosion in magnesium-canned fuel rodsWhen nuclear fuel elements  -  containing Mg, graphite and Zircaloy  -  are stored in water there is the danger of contact corrosion of Mg in contact wit graphite; in partcular when cholorides are present (even in traces) there exists the danger of pitting corrosion. Only at pH values 〉 11,5 a bydroxide layer is formed which yields a certain protection. The pitting potential in alkaline waters is shifted to more negative values with incrasing chloride contents; this displacement can be prevented by inhiitors. Most efficient is the addition of sodium carbonate which gives rise to the formation of a protective hydromagnesite layer.
    Notes: Bei Lagerung verbrauchter Brennstoffelemente  -  Werkstoffe Mg, Graphit, Zircaloy  -  in Wasser besteht die Gefahr der Kontaktkorrosion von Mg bei Kontakt mit Graphit; besonders bei Anwesenheit von Chloriden besteht Lochfraßgefahr. Erst bei pH Werten 〉 11,5 entsteht eine Hydroxidschicht, die einen gewissen Schutz bewirkt. Das Lochfraßpotential im alkalischen Wasser verschiebt sich mit zunehmendem Chloridgebalt stark in den Bereich negativer Werte, was durch Inhibitoren verhindert werden kann. Am günstigsten ist Zusatz von Natriumcarbonat, das zur Bildung eines Schutzfilms aus Hydromagnesit führt.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 30 (1979), S. 713-722 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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