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  • Electronic Resource  (32)
  • 1975-1979  (32)
  • 1976  (14)
  • 1975  (18)
  • Chemistry  (32)
  • 1
    Electronic Resource
    Electronic Resource
    A method for measuring sedimentation and diffusion of macromolecules in capillary tubes by total intensity and quasi-elastic light-scattering techniquesPresented in part at the Symposium on New Generation Instrumentation in Rheology, Rheology Society, Cincinnati, Ohio, January 1973, by M. H. Birnboim. (1975)
    New York : Wiley-Blackwell
    Biopolymers 14 (1975), S. 419-430 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Light scattered from a macromolecular solution in a capillary tube is used to determine both the sedimentation and translational diffusion coefficients. The capillary tube is spun in a preparative centrifuge, removed, and placed in a light-scattering photometer equipped with a scanning mechanism. The intensity distribution of scattered light along the tube represents the concentration profile in the tube and provides the measure of boundary migration. The sedimentation coefficient is determined from this measure and the applied centrifugal field. The diffusion coefficient is obtained from a time-autocorrelation analysis of fluctuations in intensity of light scattered from any fixed point of the profile. These coefficients were obtained for two monodisperse systems, R17 bacteriophage and 28s ribosomal rat liver RNA. The molecular weights obtained from ratios of these coefficients are in good agreement with literature values. In the sedimentation analysis, deviations from linearity between boundary displacement and applied field were found to be less than 1%. This precision confirms that the boundary is stable for the capillary geometry even in the absence of a preformed density gradient. The sedimentation coefficients of identical samples were also measured with the Spinco Model E analytical ultracentrifuge; results of the two methods agree to within 4%.As a consequence of the capillary tube geometry and light-scattering detection, sedimentation coefficients can be obtained from sample volumes of less than 100 μl. This detection techniques is thus far demonstrated to be at least an order of magnitude more sensitive than Schlieren optics, thereby useful when uv absorption is not applicable. For diffusion measurements there are also several inherent advantages. The diffusion coefficient is obtained from the identical sample, and scanning provides the capability to measure D from various parts of the sedimentation profiles and thereby directly explore concentration dependence, homogeneity, and integrity of the sample. The capillary tube with a layer of silicone oil over the sample and centrifugation provides an effective method to cleanse the solution and trap all dust.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.1975.360140214
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  • 2
    Electronic Resource
    Electronic Resource
    Di- und Polyaminozucker, XXI. Synthese von Derivaten der 2,4-Diamino-2,3,4-tridesoxy-D-ribo-hexose (1975)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 108 (1975), S. 3397-3411 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Di-and Polyamino Sugars, XXI. Synthesis of Derivatives of 2,4-Diamino-2,3,4-trideoxy-D-ribo-hexoseStarting with D-glucose the title compound has been synthesized as its di-N-acetyl. -trifluoroacetyl and N,N′-bis(2,4-dinitrophenyl) derivative. The free sugar could not be obtained in a pure state.
    Notes: Die Titelverbindung wurde, ausgehend von D-Glucose, in Form ihres Di-N-acetyl-, -trifluoracetyl- und ihres N,N′-Bis(2,4-dinitrophenyl)-Derivates erhalten. Reindarstellung des freien Zuckers gelang nicht.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19751081031
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  • 3
    Electronic Resource
    Electronic Resource
    Heterocyclische Siebenring-Verbindungen, XVI. Synthese gezielt 3,5-substituierter 4-Phenyl-1-benzothiepine (1975)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 108 (1975), S. 3596-3610 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Heterocyclic Seven-membered Ring Compounds, XVI. Synthesis of 3,5-Substituted 4-Phenyl-1-benzothiepins4-Phenyl-1-benzothiepins 7 and 8 are synthesized starting from their 5-methoxy-2,3-dihydro-precursor 2; using the 2,5-dihydro-intermediate 12 yields the 4-phenyl-1-benzothiepins 13 and 14. The 1-benzothiepin 17 can be obtained from the diketone 1 directly. The 3-cyano-substituted compound 22 is prepared from its 2,5-dihydro-precursor 21. Some ring-contraction and ring-cleavage reactions of the heterocyclic seven-membered ring-system are described.
    Notes: Die 5-Methoxy-2,3-dihydro-Vorstufe 2 wird in die 4-Phenyl-1-benzothiepine 7 und 8 übergeführt; aus der 2,5-Dihydro-Vorstufe 12 werden die 4-Phenyl-1-benzothiepine 13 und 14 dargestellt. Das 1-Benzothiepin 17 wird direkt aus dem Siebenring-Diketon 1 erhalten. Das 3-cyan-substituierte 1-Benzothiepin 22 erhält man aus der 2,5-Dihydro-Vorstufe 21. Es werden einige Ringverengungsbzw. Ringspaltungsreaktionen des heterocyclischen Siebenring-Systems beschrieben.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19751081121
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  • 4
    Electronic Resource
    Electronic Resource
    Beiträge zur Chemie des Indols, VIII. Decarboxylierungen einiger 1-Alkyl-2-carboxy-3-indolessigsäuren sowie Synthese eines 5-Thiocyanato-2,3-dihydroindols (1975)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 108 (1975), S. 3538-3542 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Not mentioned2a-d, easily produced from the N-alkyl-N-phenylhydrazines 1a-d and 2-oxoglutaric acid, are decarboxylated to the compounds 4a-d in high yields. 2a is reduced to the 2,3-dihydro compound 3a and reacts via the amide 5a to the 5-thiocyanato derivative 6a.
    Notes: Contributions to the Chemistry of Indole, VIII. Decarboxylations of Some 1-Alkyl-2-carboxy-3-indolacetic Acids and Synthesis of a 5-Thiocyanato-2,3-dihydroindole-d, leicht darstellbar aus N-Alkyl-N-phenylhydrazin und 2-Oxoglutarsäure, werden mit hoher Ausbeute zu 4a-d decarboxyliert. 2a wird zum Dihydroindol 3a reduziert und über das Amid 5a zum 5-Thiocyanatoderivat 6a umgesetzt.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19751081115
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  • 5
    Electronic Resource
    Electronic Resource
    Enhydrazine, 131) Einige Produkte aus 3-Hydroxy-1-methyl-5-pyrazolcarbonsäure- methylester und 1-Benzyl-3-hydroxypyrazol (1976)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 109 (1976), S. 268-273 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Enehydrazines, 131) Some Products from Methyl 3-Hydroxy-1-methyl-5-pyrazolecarboxylate and 1-Benzyl-3-hydroxypyrazoleSome esters and ethers of the 3-pyrazolones 1a, 2c and6a are Prepared. They are derived from the tautomeric 3-hydroxypyrazole forms in which the free starting compounds mostly occur. Some substitutions in 4-position are likewise described.
    Notes: Es werden einige Ester und Äther der 3-Pyrazolone 1a, 2c und 6a dargestellt, die sich von der tautomeren 3-Hydroxypyrazol-Form herleiten, in der auch die freien Ausgangsverbindungen vorliegen. Einige Substitutionen in 4-Stellung der 3-Hydroxypyrazole werden ebenfalls beschrieben.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19761090127
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  • 6
    Electronic Resource
    Electronic Resource
    Polymere mit dem Zentralatom eines makrocyclus in der hauptkette, 2.1. Mitteilung: cf.1. Polykondensationsreaktionen mit Germaniumkomplexen des Phthalocyanins und meso-Tetraphenylporphins (1975)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 176 (1975), S. 831-847 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Dihydroxy(phthalocyanino)germanium (1b) and Dihydroxy(tetraphenylporphino)germanium (3b) react with different monovalent alcohols to afford low-molecular bisalkoxyderivatives (1c-f and 3c-h). With bivalent alcohols and phenols polymers of the structure 5 and 6 or 8a, 9a and 8b, 9b, resp., are obtained.Dichloro(phthalocyanino)germanium (1a) and Dichlor(tetraphenylporphino)germanium (3a) react also with phenol, resp. hydroquinone, to give low-molecular and polymeric phenoxy-derivatives. The reaction of 1b and 3b with mono- and dibasic carboxylic acids leads to the corresponding esters.Dehydration of 3b gives polymeric porphin 15.The IR-spectra of the prepared compounds are discussed and compared with the analogous complexes of hemiporphyrazingermanium.Thermogravimetric and semiconductive measurements (σ298K = 10-10 - 10-15Ω-1 cm-1) are described.
    Notes: Dihydroxyphthalocyaningermanium (1b) und Dihydroxytetraphenylporphingermanium (3b) werden mit verschiedenen einwertigen Alkoholen zu den niedermolekularen Bisalkoxy-Derivaten (1c-f bzw. 3c-h) umgesetzt. Mit zweiwertigen Alkoholen und Phenolen können Polymere der Struktur 5 und 6 bzw. 8a, 9a und 8b, 9b erhalten werden.Dichlorphthalocyaningermanium (1a) und Dichlortetraphenylporphingermanium (3a) reagieren mit Phenol bzw. Hydrochinon ebenfalls zu niedermolekularen und polymeren Phenoxy-Derivaten. Die Umsetzung von 1b und 3b mit ein- und zweibasischen Carbonsäuren führt zu den entsprechenden Estern.Durch Dehydratisierung von 3b kann das polymere Porphin 15 hergestellt werden.Die IR-Spektren der dargestellten Verbindungen werden im Vergleich zu den analogen Hemiporphyrazingermaniumkomplexen diskutiert. Thermogravimetrische und Halbleitermessungen (σ298 K = 10-10 - 10-15Ω-1 cm-1) werden beschrieben.
    Additional Material: 6 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1975.021760401
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  • 7
    Electronic Resource
    Electronic Resource
    Polymere mit dem zentralatom eines makrocyclus in der hauptkette, 3.2. Mitteilung: cf.2.Polykondensationsreaktionen mit zinnkomplexen des meso-tetraphenylporphins, phthalocyanins und hemiporphyrazins (1975)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 176 (1975), S. 1919-1927 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Dihydroxy(meso-tetraphenylporphino)tin (1b), dihydroxy(phthalocyanino)tin (1d), and dihydroxy(hemiporphyrazino)tin (1f) react with bivalent phenols to afford polymers of type B. With 1,2-ethanediol and 1b low molecular compound 3 is obtained, which eliminates 1,2-ethanediol to give poly[oxyethyleneoxy(meso-tetraphenylporphin)stannandiyl] (4). Dehydration of the dihydroxy compounds 1b, 1d, 1f leads to polymers of type C. The IR-spectra of the prepared compounds are discussed; thermogravimetric and semiconductive measurements (σ298K≈10-6-10-16Ω-1cm-1) are described and compared with the analogous complexes of germanium.
    Notes: Dihydroxy-meso-tetraphenylporphinzinn (1b), Dihydroxyphthalocyaninzinn (1d) und Dihydroxyhemiporphyrazinzinn (1f) reagieren mit zweiwertigen Phenolen zu Polymeren des Typs B. Aus Äthylenglykol und 1b läßt sich die niedermolekulare Verbindung 3 erhalten, die unter Äthylenglykolabspaltung Poly[oxyäthylenoxy(meso-tetraphenylporphin)stannandiyl] (4) ergibt.Durch Dehydratation der Dihydroxy-Verbindungen 1b, 1d, 1f lassen sich Polymere des Typs C synthetisieren.Die IR-Spektren der dargestellten Verbindungen werden diskutiert; thermogravimetrische und Halbleitermessungen (σ298K≈10-6-10-16Ω-1cm-1) werden beschrieben und mit den analogen Germaniumverbindungen verglichen.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1975.021760702
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  • 8
    Electronic Resource
    Electronic Resource
    Comments on microbial growth rate (1975)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 17 (1975), S. 279-283 
    Details
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260170214
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  • 9
    Electronic Resource
    Electronic Resource
    Dynamics of mixed populations having complementary metabolism (1975)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 17 (1975), S. 1065-1081 
    Details
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The dynamics of a system of two microbial populations having complementary metabolism are investigated by means of simple mathematical models of growth. Complementary metabolism as used here means that each population produces a substance - not present in the initial or feed medium - required by the other for growth. The simple models indicate that (1) something other than lack of the substrate or growth factor produced by its partner must limit the growth of at least one population and (2) the coexistence steady state of such populations in continuous culture is not stable with respect to large perturbations, though it is stable with respect to a wide range of perturbations.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260170709
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  • 10
    Electronic Resource
    Electronic Resource
    Mass transfer from swarms of bubbles or drops with chemical reactions in continuous phase (1976)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 22 (1976), S. 925-927 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690220519
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