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  • Electronic Resource  (13)
  • 2000-2004
  • 1990-1994  (13)
  • 1993  (13)
  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 2272-2282 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Measurements of the temperature and time dependence of visible diode laser transmission and reflection are combined with transmission electron microscopy (TEM) to study the crystallization of two 75 nm Ge-Te thin films. Near-stoichiometric Ge48Te52 transforms by the rapid growth of crystals through the film thickness followed by 2D growth in the film plane. Changes in film reflection and transmission are directly related to the volume fraction transformed. The optical measurements are interpreted in terms of classical Johnson–Mehl–Avrami kinetics. A Kissinger analysis gives an activation energy for crystallization of 1.7 eV. Isothermal measurements lead to an Avrami exponent of 4.5. The data are modeled using a numerical temperature-dependent expression developed by Greer [Acta Metall. 30, 171 (1982)]. Off-stoichiometric Ge54Te46 films show markedly different crystallization behavior. Transmission and reflection measurements indicate that the transformation proceeds by rapid growth of a crystalline layer at the free surface of the film followed by 1D growth of this layer through the film. The observation is confirmed by TEM imaging and diffraction. This work shows that reflection and transmission measurements can be an effective method for the study of crystallization kinetics of amorphous thin films, particularly when more traditional calorimetric methods cannot be employed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 2590-2597 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: An investigation of the electrical and microstructural characteristics of the Ti contact on silicon has been carried out. The presence of As in Ti/n+-Si samples was found to retard the formation of polycrystalline silicide (p-silicide) compared with that in Ti/p+-Si samples with BF2+ implantation. Amorphous interlayers (a-interlayers) were found to be present in both Ti/n-Si and Ti/p-Si samples annealed at temperatures of and lower than 450 °C. Although the Schottky barrier heights (SBH's) vary for about 0.05–0.08 eV for samples annealed over a temperature range from room temperature to 900 °C, SBH's at the a-interlayer/n-Si and a-interlayer/p-Si were measured to be about 0.52–0.54 and 0.59–0.57 eV, respectively. The specific contact resistance (ρc) in the Ti/n+-Si system was measured to be the lowest with a value of 1.4×10−7 Ω cm2 when the a interlayer is present. In Ti/p+-Si system, the minimum ρc is about 3×10−7 Ω cm2. The variation in contact resistance with annealing temperature for both Ti/n+-Si and Ti/p+-Si samples is correlated to the change in dopant concentration beneath the contacts as well as microstructures. In the temperature regime where the a interlayer is in contact with the silicon substrate, the junction diode leakage current densities (Jleak's) are considerably lower than those in samples annealed at higher temperatures. The Jleak at −6 V reverse bias is lower than 1 nA/cm2. The breakdown voltage is about 14 V (16 V) for the n+/p (p+/n) junction. The thickness of consumed Si is less in samples annealed at low temperature, and the a-interlayer/Si or p-silicide/Si interface is accordingly farther away from the junction as well as the end-of-range defects. The interface of p-silicide/Si is rougher than that of a-interlayer/Si. In addition, the roughness of the p-silicide/Si interface increases with annealing temperature. For both p+/n and n+/p junctions annealed at 900 °C, rough p-silicide/Si interfaces are thought to lead to spiking and increase the leakage currents.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 2916-2920 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The dependence of majority carrier mobility on carrier concentration at 77 K in Hg0.78Cd0.22Te has been studied by Hall measurements on about 190 n-type and 360 p-type liquid phase epitaxial films. The n-type films were indium doped with the carrier concentration varying from 1×1014 to 2×1016 cm−3. The measured electron mobility changed from 2×105 to 8×104 cm2/V s. The p-type films were undoped (Hg vacancy) with the carrier concentration varying from 2×1015 to 3×1017 cm−3. The measured hole mobility changed from 600 to 200 cm2/V s. By comparing calculated mobility curves with the experimental data, we found that the major scattering mechanisms for electron mobility in n-type materials were polar optical phonon, ionized impurity, and alloy disorder scatterings. These three scattering mechanisms also dominate the hole mobility in p-type materials at 77 K. It was also found that a model with Hg vacancy as doubly ionized shallow acceptors fitted very well the hole mobility versus carrier concentration data.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    Journal of Mathematical Physics 34 (1993), S. 3012-3029 
    ISSN: 1089-7658
    Source: AIP Digital Archive
    Topics: Mathematics , Physics
    Notes: The Boltzmann equation has been used in the literature to show that the entropy differential consists of a Pfaffian form in the space of conserved and nonconserved variables (moments) and a term related to the energy dissipation due to the irreversible processes in the system. The said Pfaffian form is called the compensation differential. In this paper, the integrability of the compensation differential is examined by means of the theory of differential forms. The integrability conditions turn out to be generalized forms of the Maxwell relations in equilibrium thermodynamics. It is also shown that the generalized form of the Gibbs–Duhem relation can be seen as an equivalent of the integrability conditions. This conclusion is drawn by using the notion of homotopy operator. The Caratheodory principle is also applied to make the connection with the second law of thermodynamics more intimate than the direct but mathematically more abstract approach using the integrability conditions. The meaning of the integrating factor is clarified by using the notion of contact temperature since the integrating factor, a mathematical function, is endowed with a thermodynamically operational meaning when it is identified with the inverse local absolute temperature through the notion of contact temperature, and the compensation differential is thereby made a thermodynamically meaningful equation governing nonequilibrium processes. Through this study it is shown that in irreversible thermodynamics the compensation differential can play the role parallel to the equilibrium Gibbs relation for the entropy in equilibrium thermodynamics and thus can serve as the foundation on which to formulate a theory of irreversible processes.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 62 (1993), S. 3354-3356 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A series of Ag-doped Tl2Ba2Ca2Cu3Oy superconducting oxides were prepared by a solid-state reaction and the influence of Ag2O content, with a varying molar ratio which ranged from 0 to 1.0, was also investigated. The normal-state resistance of the samples decreased with an increase in the content of Ag2O additive, while the critical superconducting temperatures of the Ag-doped samples increased once the Ag2O content was increased. The doping of the silver oxide was indicated from the results of the x-ray diffraction pattern to be favorable to the formation of the three CuO layers with a high-Tc phase Tl2Ba2Ca2Cu3Oy. The diamagnetic property of the samples was also confirmed by the magnetic measurements to become enhanced by doping with silver oxide. The platelike grains of Tl2 Ba2CaCu2Oy phase were observed from scanning electron micrographs to be primarily present in the undoped sample, while the amount of the needlelike Tl2Ba2Ca2Cu3Oy grain increased with an increase in the doping amount of Ag2O.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of biomedical science 1 (1993), S. 2-6 
    ISSN: 1423-0127
    Keywords: Insulin receptor ; Protein kinase ; Gene expression
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract Two Chinese hamster ovary (CHO) cell lines stably transfected with human insulin receptor cDNA, CHO-wt and CHO-mut, which express an equivalent number of normal and kinase-defective human insulin receptors, respectively, were used to assess the roles of insulin receptor tyrosine kinase activity in insulin-regulated gene expression. The effect of insulin on gene-33-promoter-driven chloramphenicol acetyltransferase (CAT), RSVLTR-driven β-galactosidase (pRSVLTR-βgal) and SV40 late-promoter-driven hepatitis B surface antigen (pMLSV2HBsAg) were examined in CHO-wt and CHO-mut cells. Insulin-stimulated gene 33 promoter is 10- to 50-fold more effective in CHO-wt cells than that in parental CHO cells. However, no enhancement of insulin sensitivity of gene 33 promoter in CHO-mut cells relative to parental CHO cells was found. Similar phenomena were also observed, in that insulin regulated pRSVLTR-βgal and pMLSV2HBsAg in these three CHO lines. Our data indicated that the protein kinase activity of the insulin receptor is essential for the stimulatory activity of insulin toward the activities of different promoters.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1423-0127
    Keywords: Chronic type B hepatitis ; Mixed viral strains in acute exacerbations ; Hepatitis B virus reinfection
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract Chronic hepatitis B virus (HBV) infections are frequently associated with exacerbations of hepatitis of which the majority are due to reactivation of viral activity. Variation in a viral genome during persistent infection has been shown to be a possible cause for reactivation. In this study, we have found another possible mechanism. HBV in a patient with repeated exacerbations was isolated at six different times during follow-up and was characterized by polymerase chain reaction and DNA sequencing. The first episode of exacerbation was accompanied with increased replication of an HBV strain. The second episode, however, was associated with the sudden appearance of an HBV strain that displayed enough sequence variations to warrant the designation as a separate strain. The results suggested a reinfection event by another independent HBV. Subsequent exacerbations were then related to coactivation of both viral stains. These observations provide significant information toward understanding the acute exacerbations of chronic type B hepatitis.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Social psychiatry and psychiatric epidemiology 28 (1993), S. 134-141 
    ISSN: 1433-9285
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary This article reports the development of an acculturation scale for Southeast Asian immigrants. From factor analyses of responses on 13 items obtained from samples of three different Southeast Asian ethnic groups, i.e., Cambodians, Laotians, and Vietnamese, two subscales were derived: (1) proficiency in languages (land of origin versus English), and (2) language, social and food (LSF) preferences. Inter-item reliability of the scales was demonstrated for each of the three ethnic groups, with Cronbach alpha coefficients of 0.76 or above. Construct validity was also established within each of the three ethnic groups by demonstrating expected associations of the subscales with current age, years in the USA, total years of education, percentage of lifetime in the USA, and age on entering the USA. Multivariate analyses within each of the ethnic groups revealed that, once controlling for years of education, percentage of lifetime in the USA, and type of health care coverage, although not significant for the Cambodians (P=0.08) males tended to show higher scores for the proficiency in language subscale in comparison to females. Similar multivariate analyses for the LSF preference subscale showed that although slightly higher for the males, the differences between the genders was not significant for the Cambodians (P=0.78); both the Laotian (P=0.23) and Vietnamese (P=0.01) females showed higher scores in comparison to males although only just reaching significance for the Vietnamese.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 28 (1993), S. 3329-3334 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The relation between vacancy concentration, C v and tensile plastic strain, ɛ, has been constantly expressed as C v ∞ ɛ m . To take into account the grain-size effect, we have recently proposed that C∞ ɛβv ∞ϱm, where ϱm is the mobile dislocation density. With the conventional expression that ϱm d −n , where d is the average grain size, the strain and grain-size dependence of vacancy concentration appears to be C v ∞ ɛβγ d -nγ. This equation has proved effective in rationalizing the onset strain, ɛc, and stress amplitude, Δσ, of flow instability associated with the Portevin-LeChatelier effect of substitutional f c c alloys, where ɛc and Δσ are described by $$\dot \varepsilon \propto \varepsilon _c^{\beta (1/2 + \gamma )} d^{ - n(1/2 + \gamma )} T^{ - 1} exp( - Q/kT)$$ and $$\Delta \sigma \propto \left[ {\dot \varepsilon ^{ - 1} \varepsilon _c^{\beta (1/2 + \gamma )} d^{ - n(1/2 + \gamma )} T^{ - 1} exp( - Q/kT)} \right]^{2/3} $$ in which $$\Delta \sigma \gamma \propto \left[ {\varepsilon ^{\beta \gamma } d^{ - n\gamma } t_a T^{ - 1} exp( - Q/kT)} \right]^{2/3} $$ , T, Q and k are the strain rate, temperature, Boltzmann constant and activation energy for solute migration, respectively. Using the same concept, we have obtained $$\Delta \sigma \gamma \propto \left[ {\varepsilon ^{\beta \gamma } d^{ - n\gamma } t_a T^{ - 1} exp( - Q/kT)} \right]^{2/3} $$ to rationalize the increment of stress drop, Δσγ, observed at the instant of reloading after a static ageing time of t a. By adopting the above three equations, the strain-ageing data of two Al-Mg alloys in this study reveal that the vacancy concentration which is responsible for strain ageing is lower than the reported data from electrical resistivity measurements. This result is in agreement with the idea of migration of a vacancy-solute complex which has been proposed in the literature.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 49 (1993), S. 1197-1203 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This study was to improve the performances of nylon 4 membranes for washing waste-water treatment of nuclear power plants, e.g., removal of detergent and salt by membranes. The effects of the degree of grafting and ionization on the reverse osmosis performances of acrylic acid (AA)-grafted nylon 4 membranes by γ-ray irradiation modification were investigated. The relationships of operating conditions, such as feed concentrations of salt and detergent, operating temperature, and pressure, and the performances of water flux and solute rejection of the prepared membranes were obtained. Water flux of the prepared membranes was highly sensitive with the operating temperature. It was found that an increase in the operating pressure could increase the water flux and the impaction effect directly. Water flux and salt rejection were significantly improved by both ionized and nonionized AA-grafted nylon 4 membranes compared to ungrafted nylon 4 membranes. Water flux increased rapidly and solute rejection dropped off slightly as the grafted membranes were ionized. The 100% detergent rejection could be obtained by the nonionized AA-grafted nylon 4 membranes with 38.6 and 69.6% degrees of grafting under various operating conditions. Results obtained showed that these modified nylon 4 membranes were usable for washing waste-water treatment of nuclear power plants. © 1993 John Wiley & Sons, Inc.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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