ISSN:
1572-879X
Schlagwort(e):
solid base
;
KNH2 loaded on alumina
;
Si-C bond formation
;
toluene
;
diethylsilane
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Abstract The catalytic substitution at silicon occurs in the reaction of toluene and diethylsilane in the presence of KNH2 loaded on alumina, the yield of benzyldiethylsilane being 85% in 40 h at 329 K. Benzene also reacted with diethylsilane in the presence of the catalyst to afford a 7.5% yield of benzyl diethylsilane in 20 h at 329 K.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1023/A:1019006816637
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