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  • Electronic Resource  (2)
  • 1990-1994  (2)
  • 68.55.Gi  (1)
  • Environmental materials analysis  (1)
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  • Electronic Resource  (2)
Years
  • 1990-1994  (2)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 93 (1994), S. 141-146 
    ISSN: 1434-6036
    Keywords: 68.55.Gi ; 79.20.Rf ; 61.14.-X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Ar+ sputtering of an Cu(111) surface while simultaneously supplying Mo atoms is known to induce an oriented growth of Mo thin crystals, or “seed-layers”, on evolving conical Cu protrusions. The seed-layers thus formed are shown to be dual-oriented, or bicrystalline, consisting of columnar crystallites grown homo-epitaxially. The orientation relationship between the two types of crystallites was (100)I ‖ (111)II with [001]I ‖ [110]II, and this bicrystallinity probably resulted from a non-uniform charge-up of the layers' growth front. As concluded from high-resolution electron microscopy, the Mo(100) stacking is elastically converted into the Mo(111) stacking and vice versa, under the influence of tensile stress. The homo-epitaxy that the seed-layers exhibited is believed to reflect the mutual convertibility of the Mo(100) and (111) stackings.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1612-1112
    Keywords: Ion-exchange chromatography ; Anion-exchange ; Bismuth preconcentration ; Environmental materials analysis ; Graphite furnace atomic absorption spectrometry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Anion-exchange preconcentration techniques have been developed for traces of bismuth in environmental materials. Biological samples are opened up with a mixture of acids and silicates by fusion with a lithium carbonate-boric acid mixture. Bismuth is then separated from the sample matrices by anion-exchange from (a) oxalic acid-hydrochloric acid solution or (b) magnesium nitrate solution. Selectively adsorbed bismuth is removed from the column and quantified by graphite furnace atomic absorption spectrometry using palladium nitrate as a matrix modifier. Detection limit is 16 pg for 1% absorption. The developed methods were applied to several environmental reference materials for traces of bismuth.
    Type of Medium: Electronic Resource
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