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  • 1
    ISSN: 1423-0445
    Keywords: mandibular glands ; chemotaxonomy ; chirality ; synthesis ; 2-methyl-1-hexanol ; Hymenoptera ; Formicidae ; Formicinae ; Cataglyphis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Summary In all the species of theCataglyphis bicolor group examined yet, i.e.C. bicolor, C. diehli, C. isis, C. nodus, andC. viaticus, 2-methyl-1-hexanol is the characteristic substance and almost the only substance found in the mandibular glands. Its chirality has been determined inC. bicolor and shown to be exclusively (S)-2-methyl-1-hexanol.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-1561
    Keywords: 4-Methyl-3-heptanone ; 4-methyl-3-heptanol ; Atta sexdens rubropilosa ; male ; female ; chirality ; Hymenoptera ; Formicidae ; gas chromatography-mass spectrometry ; chiral column gas chromatography
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract (S)-;(+)-4-Methyl-3-heptanone is the principal component in the secretion from the mandibular glands of unmated and mated males and females ofAtta sexdens rubropilosa. In mated and unmated females, it is essentially the only component in the glandular secretion. In unmated males up to 50% of the secretion is a mixture of (3S, 4S)- and (3R, 4S)-4-methyl-3-heptanol. After mating, the amount of alcohol in the males decreases markedly.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 16 (1933), S. 1201-1208 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 16 (1933), S. 54-69 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 16 (1933), S. 468-478 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 16 (1933), S. 375-382 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurde gezeigt, dass bei der Fällung der Schwermetallferro-cyanide aus verdünnter Lösung (Konzentration der Metallsalze und des Ferrocyanids 0,01- bis 0,005-m.) charakteristische Maxima der Viskosität auftreten, deren Lage angenähert stöchiometrischen Verhältnissen der reagierenden Ionen entspricht, wobei aber der Permutit-charakter der Niederschläge eine Rolle spielt.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0887-6134
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dinucleoside monophosphates bearing usual protecting groups at the exocyclic amino functions of the heterocyclic bases, the 5′-hydroxy group, the phosphate moiety and the O-6-position of the guanine ring have been analysed by FAB mass specrometry in the negative ion mode. These non-charged key intermediates for oligodeoxynucleotide synthesis exhibit very simple spectra in the mass range of m/z 400-1500 using tetra-ethylene glycol as matrix. Most of the observed ions could easily be assigned. Apart from deprotonated molecular ions sequence specific ions arising from C-O-P bond cleavage and ions derived from loss of protecting groups were observed. The simplicity of spectra interpretation makes FAB mass spectrometry to a rapid and valuable tool for unambiguous identification of dimeric synthons for oligonucleotide synthesis.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 3 (1980), S. 415-416 
    ISSN: 0935-6304
    Keywords: Gas chromatography/mass spectrometry ; Volatile sulfur compounds from waste water ; Adsorption of air samples on tenax GC ; Mechanism of corrosion of concrete ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 24 (1993), S. 131-141 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Arc-PVD-Coating of Cemented Carbides and Analysis of their Functional Behaviour in Interrupted Cut MachiningInterrupted machining of quenched and tempered steel demands the application of tools with high resistance against mechanically and tribologically induced wear. These demands can not be fully satisfied by uncoated carbides. Also CVD-coatings give only some improvement due to a certain embrittlement of the substrate during the coating process. PVD-coatings deposited at low temperatures without affection of the substrate lower the influence of the relevant wear mechanisms preferably at moderate cutting speeds.The combination of tough substrates with structural and compositional optimized coatings results in a multiplication of tool life within the whole range of low and medium cutting speeds. Coatings with homogenious structure, compressive residual stresses and high content of metalloides ensure excellent resistance against wear.Titanium-carbonitride deposited on carbide was found to be superiour compared with other carbonitride, nitride and carbide coatings within the system Ti—Zr—C—N due to excellent tribological properties. It was optimal suited for the interrupted cut application.
    Notes: Die Zerspanung von höherfesten Stahlwerkstoffen in unterbrochenen Schnitten stellt an die Werkzeuge hohe mechanische und tribologische Anforderungen, denen unbeschichtete Hartmetalle in vielen Fällen nicht gerecht werden können. Während sich bei der Zerspanung von höherfestem Stahl in stark unterbrochenen Schnitten durch die CVD-Beschichtung von Hartmetallen auf-grund prozeßbedingter Versprödungseffekte kaum Leistungssteigerungen erzielen lassen, können PVD-Hartstoffbeschichtungen, die bei substratschonend niedrigen Prozeßtemperaturen abgeschieden werden, dem Auftreten der relevanten Schädigungsmechanismen besonders bei niedrigen und mittleren Schnittgeschwindigkeiten entscheidend entgegenwirken.Insbesondere mit zähen Substratsorten sowie mit strukturell und kompositionell optimierten Schichten können Standzeitvervielfachungen im gesamten unteren und mittleren Schnittgeschwindigkeitsbereich erzielt werden. Homogene Schichtstrukturen, hohe Druckeigenspannungen und hohe Metalloidgehalte der Hartstoff-schichten gewährleisten eine hohe Verschleißfestigkeit. Titankarbonitrid zeichnet sich auf Hartmetallen gegenüber anderen karbonitridischen, nitridischen und karbidischen Schichten des Systems Ti—Zr—C—N durch ein besonders günstiges tribologisches Verhalten aus und hat sich als optimaler Beschichtungswerkstoff für unterbrochene Schnitte erwiesen.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 553-556 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary, glass ; Carbohydrate enantiomer separation ; New chiral stationary phases ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: New chiral polymers have been prepared by conversion of cyano groups of polysiloxanes XE-60 and OV-225 into carboxylic groups and subsequent coupling to give the respective S-valine-R-α-phenyl-ethyl amide. In contrast to the corresponding stationary phases with S-α-phenylethyl amide groups, which have been used for the resoultion of trifluoroacetylated hexose derivatives, the new phase show high enantioselectivity for pentose and 6-deoxyhexose derivatives.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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