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  • Electronic Resource  (8)
  • Polysulfanes  (2)
  • Polysulfides  (2)
  • Polythionates  (2)
  • Strukturaufklärung  (2)
  • X-ray structural analysis  (2)
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  • Electronic Resource  (8)
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  • 1
    Electronic Resource
    Electronic Resource
    Search for polythionates in cultures of Chromatium vinosum after sulfide incubation (1990)
    Springer
    Archives of microbiology 153 (1990), S. 432-437 
    Details
    ISSN: 1432-072X
    Keywords: Chromatium vinosum ; Phototrophic bacteria ; Polysulfides ; Polythionates ; Elemental sulfur ; Sulfur globules ; Ion chromatography ; HPLC
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Cultures of Chromatium vinosum, devoid of sulfur globules, were supplemented with sulfide and incubated under anoxic conditions in the light. The concentrations of sulfide, polysulfides, thiosulfate, polythionates and elemental sulfur (sulfur rings) were monitored for 3 days by ion-chromatography and reversed-phase HPLC. While sulfide disappeared rapidly, thiosulfate and elemental sulfur (S6, S7 S8 rings) were formed. After sulfide depletion, the concentration of thiosulfate decreased fairly rapidly, but elemental sulfur was oxidized very slowly to sulfate. Neither polysulfides (S x 2− ), polythionates (SnO 6 2− , n=4–6), nor other polysulfur compounds could be detected, which is in accordance with the fact that sulfide-grown cells were able to oxidize polysulfide without lag. The nature of the intracellular sulfur globules is discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00248423
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  • 2
    Electronic Resource
    Electronic Resource
    Thiosulfate and tetrathionate degradation as well as biofilm generation by Thiobacillus intermedius and Thiobacillus versutus studied by microcalorimetry, HPLC, and ion-pair chromatography (1994)
    Springer
    Archives of microbiology 161 (1994), S. 116-125 
    Details
    ISSN: 1432-072X
    Keywords: Thiobacillus intermedius ; Thiobacillus versutus ; Thiosulfate ; Polythionates ; Ion-pair chromatography ; Microcalorimetry ; Biofilm
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The growth of Thiobacillus (T.) intermedius strain K12 and Thiobacillus versutus strain DSM 582 on thiosulfate and tetrathionate was studied combining on-line measurements of metabolic activity and sulfur compound analysis. Most results indicate that T. intermedius oxidized thiosulfate via tetrathionate to sulfate. Concomittantly, sulfur compound intermediates like triand pentathionate were detectable. The formation is probably the result of highly reactive sulfane monosulfonic acids. The formation of tetrathionate allows the cells to buffer temporarily the proton excretion from sulfuric acid production. With T. versutus intermediate sulfur compounds were not detectable, however, sulfur was detectable. The possibility of a thiosulfate oxidation via dithionate, S2O inf6 sup2- , is discussed. The on-line measurement of metabolic activity by microcalorimetry enabled us to detect that cells of T. intermedius adhere to surfaces and produce a biofilm by a metabolic process whereas those of T. versutus fail to do so. The importance of the finding is discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00276471
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  • 3
    Electronic Resource
    Electronic Resource
    Preparation of Organic Polysulfanes R2Sn (n = 5, 7, 8, 9) from Sulfenyl Chlorides, RSCl, and Transition Metal Polysulfido Complexes (2000)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 2000 (2000), S. 921-928 
    Details
    ISSN: 1434-1948
    Keywords: Sulfur ; Titanium ; Zinc ; Polysulfido complexes ; Sulfur heterocycles ; Polysulfides ; Polysulfanes ; Sulfenyl chlorides ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The preparation of seven novel organic polysulfanes is reported. Bis(n-octyl)heptasulfane R2S7 1 is formed upon reaction of RSCl with [Cp2TiS5], while the corresponding nonasulfane R2S9 2 is obtained by reaction of RSSCl with [Cp2TiS5]. The bis(n-octyl)pentasulfane R2S5 3 is obtained from RSCl and [(Cp′2TiCl)2S3] by transfer of the S3 ligand at 20 °C. The new alkyl polysulfanes 1-3 have been obtained in quantitative yields. They are liquids at 20 °C, having freezing points below -50 °C, but do not form mesogenic phases. Reactions of [Cp2TiS5] with 2-naphthyl- and 4-chlorophenyl sulfenyl chloride furnish the corresponding heptasulfanes 4 and 5, respectively, which are solids at 20 °C. 1,2-Benzodisulfenyl chloride C6H4(SCl)2 reacts with [(Cp′2TiCl)2S3] to give the known 1,2,3,4,5-benzopentathiepin C6H4S5 6, with [Cp2TiS5] to give the novel 1,2,3,4,5,6,7-benzoheptathionin C6H4S7 7, and with [(TMEDA)ZnS6] to give the novel 1,2,3,4,5,6,7,8-benzooctathiecin C6H4S8 8. The cyclic polysulfanes 6-8 are solids at 20 °C and have been recovered in yields of 60-83%. The orthorhombic structure of 1,2-C6H4S7 has been investigated by single-crystal X-ray diffraction analysis. The molecules are found to be located at sites of Cs symmetry and the motif of the C2S7 heterocycle is +-+-+-+-, with the torsion angle of zero at the carbon-carbon bond. The three internuclear SS distances measure 205.0(1), 203.7(1), and 205.7(1) pm.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Große Schwefel-Stickstoff-Heterocyclen: Synthese der Schwefelimide SnNH (n = 8, 9, 11) und Strukturen von S8NH und S9NHSchwefelverbindungen, 196. Mitteilung. Diese Arbeit wurde von der Deutschen Forschungsgemeinschaft, dem Deutschen Akademischen Austauschdienst und dem Fonds der Chemischen Industrie unterstützt. 195. Mitteilung: Lit. [1]. (1996)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 108 (1996), S. 2641-2643 
    Details
    ISSN: 0044-8249
    Keywords: Schwefelverbindungen ; Stickstoffverbindungen ; Strukturaufklärung ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19961082111
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  • 5
    Electronic Resource
    Electronic Resource
    Schwefelsäure aus Schwefeltrioxid und Wasser - eine überraschend komplexe ReaktionSchwefelverbindungen, 189. Mitteilung. Für die Anfertigung der Abb. 1-4 danke ich Frau Dr. Yana Drozdova. 188. Mitteilung: M. Pridöhl, R. Steudel, J. Buschmann, P. Luger, Z. Anorg. Allg. Chem., im Druck. (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 107 (1995), S. 1433-1435 
    Details
    ISSN: 0044-8249
    Keywords: Atmosphärenchemie ; Schwefelsäure ; Schwefelverbindungen ; Strukturaufklärung ; Wasserstoffbrücken ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19951071206
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  • 6
    Electronic Resource
    Electronic Resource
    Preparation of spiro-cyclic organic polysulfanes of type C6H10Sn and x-ray structural analysis of C6H10S11, a derivative of cyclo-dodecasulfur (1996)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 622 (1996), S. 1594-1600 
    Details
    ISSN: 0044-2313
    Keywords: Organic polysulfanes ; NMR spectra ; X-ray structural analysis ; high-pressure liquid chromatography ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Darstellung spirocyclischer organischer Polysulfane des Typs C6H10Sn und Röntgenstrukturanalyse von C6H10S11Durch Reaktion von (C5H5)2Ti(μ-S2)2C6H10 3 mit S2Cl2 wurde 7,8,9,10,11,12-Hexathiaspiro[5,6]dodecan 4 hergestellt (Ausbeute 51%), das durch UV-, IR-, Raman-, Massen- und NMR-Spektren (1H, 13C) charakterisiert wurde. Die NMR-Spektren zeigen, daß der siebengliedrige CS6-Ring in Lösung Pseudorotation erleidet. Mit S7Cl2 reagiert der Komplex 3 zu 7,8,9,10,11,12,13,14,15,16,17-Undecathiaspiro-[5.11]heptadecan 5 (Ausbeute 23%). Die gelben, monoklinen Kristalle von 5 bestehen aus spirocyclischen C6H10S11-Molekülen, deren C6-Ring Sesselkonformation aufweist, während der CS11-Ring eine dem cyclo-Dodecaschwefel S12 entsprechende Konformation besitzt. Alle Glieder der homologen Reihe C6H10Sm (m = 5-14) wurden mittels HPLC charakterisiert.
    Notes: By reaction of (C5H5)2Ti(μ-S2)2C6H10 3 with S2Cl2 7,8,9,10,11,12-hexathiaspiro-[5.6]dodecane 4 is prepared (yield 51%) and characterized by UV, IR, Raman, mass, and NMR spectra (1H, 13C). The seven-membered CS6 ring undergoes pseudorotation in solution. With S7Cl2 the complex 3 yields 7,8,9,10,11,12,13,14,15,16,17-undecathiaspiro[5.11]heptadecane 5 (yield 23%). The yellow, monoclinic crystals of 5 consist of spirocyclic C6H10S11 molecules with the C6 ring in a chair-conformation while the CS11 ring is of the same conformation as cyclododecasulfur S12. UV, IR, Raman, mass and NMR-spectra of 5 are reported. A mixture of dichlorosulfanes SnCl2 (n = 1 -8) reacts with 3 to give the homologous series C6H10Sm which was characterized by reversed-phase HPLC for m = 5 - 14.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19966220924
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  • 7
    Electronic Resource
    Electronic Resource
    Sulfur Compounds. 183. A Derivative of Perthiocarbonic Acid H2CS4: X-ray structural analysis of bis(triphenylmethyl) perthiocarbonate (Ph3C)2CS4 (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 1513-1516 
    Details
    ISSN: 0044-2313
    Keywords: Perthiocarbonic acid diester ; X-ray structural analysis ; perthiocarbonate ; bis(triphenylmethyl) perthiocarbonic acid diester ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Ein Derivat der Perthiokohlensäure H2CS4: Röntgenstrukturanalyse von Bis(triphenylmethyl)perthiocarbonat (Ph3C)2CS4Die Molekülstruktur von Ph3CSSC(S)SCPh3 · CS2 wurde durch eine Röntgenstrukturanalyse bestimmt. Die Substanz kristallisiert im triklinen Kristallsystem [a = 884,9(2) pm, b = 1 039,5(2) pm, c = 2 064,6(3) pm, α = 75,86(1)°, γ = 79,83(2)°, γ = 77,31(5)°, Z = 2, Raumgruppe P1]. Die CS3-Gruppe ist planar; die S—S-Bindung (201,4 pm) bildet mit der CS3-Ebene einen Winkel von 5,7°. Der CSSC-Torsionswinkel beträgt 96,3°. (Ph3C)2CS4 wurde durch Umsetzung von TosNSCl2 (Tos = p-MeC6H4SO2) mit Ph3CSH in CS2 in Gegenwart von Triethylamin erhalten. Der Reaktionsmechanismus wird diskutiert.
    Notes: The molecular structure of Ph3CSSC(S)SCPh3 · CS2 has been determined by X-ray structural analysis. The substance crystallizes in the triclinic crystal system [a = 884.9(2) pm, b = 1 039.5(2) pm, c = 2 064.6(3) pm, α = 75.86(1)°, β = 79.83(2)°, γ = 77.31(5)°, Z = 2, space group P1]. The CS3 group is planar; the S—S-bond (201.4 pm) forms an angle of 5.7° with the CS3 plane. The torsional angle CSSC equals 96.3°. (Ph3C)2CS4 was obtained by reaction of TosNSCl2 (Tos = p-MeC6H4SO2) with Ph3CSH in CS2 in the presence of triethylamine. The reaction mechanism is discussed.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19956210913
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  • 8
    Electronic Resource
    Electronic Resource
    Crystal and Molecular Structures as well as Spectra of Two Organic Tetrasulfanes R2S4 (R = 2-benzothiazolyl and 4-chlorophenyl) (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 1021-1024 
    Details
    ISSN: 0044-2313
    Keywords: Polysulfanes ; structure ; spectra ; preparation ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Kristall- und Molekülstrukturen sowie Spektren zweier organischer Tetrasulfane R2S4 (R = 2-Benzothiazolyl und 4-Chlorphenyl)Bis(2-benzothiazolyl)tetrasulfan, hergestellt aus dem Mercaptan und S2Cl2, kristallisiert in der monoklinen Raumgruppe C2/c mit den im Abstract angegebenen Zelldimensionen. Die Moleküle haben C2-Symmetrie; das S4-Gerüst ist von all-trans-Konformation mit den Parametern dss = 202,7 (terminal) und 207,3 pm (zentral), αsss = 106,4° und τssss = 78,5°. Bis(4-chlorphenyl)tetrasulfan kristallisiert in der monoklinen Raumgruppe P21/a (s. Abstract). Die Moleküle befinden sich in allgemeinen Lagen, sind aber näherungsweise von C2-Symmetrie und ebenfalls von all-trans-Konformation mit dss = 203,6 (terminal), 206,7 (zentral) und 202,3 pm (terminal), αsss = 107,4° und 108,4° sowie τssss = 75,5°. Die intermolekularen Wechselwirkungen sind vom van der Waals-Typ. Infrarot-, Raman-, Massen- und NMR-Spektren (1H, 13C) der Verbindungen werden mitgeteilt.
    Notes: Bis(2-benzothiazolyl)tetrasulfane prepared from the mercaptane and S2Cl2 crystallizes in the monoclinic space group C2/c with a = 3513 pm, b = 577.28 pm, c = 800.0 pm, β = 98.74°, ρ = 1.64 g cm-3 (at 298 K). The molecules are of C2 symmetry with the geometrical parameters of the S4 backbone: dss = 202.7 (terminal) and 207.3 pm (central), αsss = 106.4°, τssss = 78.5°. The overall conformation is all-trans.Bis(4-chlorophenyl)tetrasulfane prepared from the mercaptane and diisopropoxydisulfane crystallizes in the monoclinic space group P21/a with a = 1237.7 pm, b = 748.4 pm, c = 1623.9 pm, β = 105.58°, ρ = 1.61 g cm-3 (at 298 K). The molecules occupy general positions but are approximately of C2 symmetry with dss = 203.6 (terminal), 206.7 (central) and 202.3 pm (terminal), αsss = 107.4° and 108.4°, τssss = 75.5° (all-trans conformation). The intermolecular interactions are of van der Waals type. Infrared, Raman, mass and NMR spectra (1H, 13C) are reported.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19956210621
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