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  • 2000-2004  (12)
  • 1990-1994
  • 2002  (12)
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  • 2000-2004  (12)
  • 1990-1994
Year
  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 91 (2002), S. 271-273 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Pseudobinary Pr1−xTbx(Fe0.6Co0.4)2 (0≤x≤0.4) cubic Laves single phases have been synthesized by melt spinning and subsequent annealing. Their structure, magnetic properties and stability have been investigated. The composition, at which the anisotropy of Pr1−xTbx(Fe0.6Co0.4)2 is compensated, is close to x=0.1. The spontaneous magnetostrictions λ111 of Pr0.9Tb0.1(Fe0.6Co0.4)2 and Pr0.8Tb0.2(Fe0.6Co0.4)2 are larger than 1500×10−6 and 1900×10−6, respectively. Pr1−xTbx(Fe0.6Co0.4)2 (0.1≤x≤0.4) ribbon-based materials with 3% epoxy resin combine high magnetostriction with significant magnetic coercivity. Pr0.9Tb0.1(Fe0.6Co0.4)2 is a promising magnetostrictive material. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 91 (2002), S. 501-505 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: High quality ZnO thin films have been grown on a Si(100) substrate by plasma enhanced chemical vapor deposition using a zinc organic source [Zn(C2H5)2] and carbon dioxide (CO2) gas mixtures at the low temperature of 180 °C. The dependence of ZnO thin film quality on the gas flow rate ratio of Zn(C2H5)2 to CO2 (GFRRZC) is studied by using x-ray diffraction (XRD), optical absorption (OA) spectra, and cathodoluminescence (CL) spectra. High quality ZnO thin films with a c-axis-oriented wurtzite structure are obtained when the GFRRZC is 0.33. XRD shows that the full width at half maximum of (0002) ZnO located at 34.42° is about 0.2°. At room temperature, a pronounced free exciton absorption peak around 365 nm is clearly observed. Also, a strong free exciton emission without deep level defect emission is observed around 385 nm, and its temperature dependence is studied from the photoluminescence spectra. These observations indicate the formation of a high quality ZnO film. Additionally, nitridation of the Si surface caused by releasing NH3 plasma into the deposition chamber is an effective way to improve film quality. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 117 (2002), S. 3081-3087 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: In this work, we present a generalized version of the semirigid vibrating rotor target (SVRT) model by including additional vibrational modes explicitly in the SVRT Hamiltonian. The inclusion of additional vibrational modes eliminates the uncertainty of fixing certain geometries of the target molecule as required in the basic SVRT model. This generalized SVRT (GSVRT) model was employed to study the benchmark reaction H+CH4 by including the umbrella mode of CH4. Influence of the umbrella mode of the reagent on reactivity is investigated. It is concluded that the inclusion of the umbrella vibrational mode of CH4 has only a small effect on the reaction from the ground state of the reagent, and essentially no effect from the excited C–H stretching vibrational state of the reagent. However, the initial excitation of the umbrella mode does give a sizable enhancement of reaction and reduces the reaction barrier by about 1.1 kcal/mol. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 116 (2002), S. 6497-6504 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: In this work, we employ the semirigid vibrating rotor target (SVRT) model to study the influence of rotational and vibrational excitation of the reagent on reactivity for the benchmark reaction H+CH4(v,j,K,n). The excitation of the pseudo H–CH3 stretching vibration of the SVRT model gives significant enhancement of reaction probability, consistent with the later position of the reaction barrier on the potential energy surface. The vibrationally thermal-averaged rate constant is much larger than the rate constant of the ground vibrational state. Detailed study of the influence of initial rotational states on reaction probability shows strong steric effect. The reaction probability is directly correlated with the angular distribution of the initial wave function determined by different angular momentum relationships among three vectors j, R, and r. The steric effect of polyatomic reactions, treated by the SVRT model, is more complex and richer than theoretical calculations involving linear molecular models. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 80 (2002), S. 1966-1968 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In this study, the interface structure of α-Fe/Nd2Fe14B nanocomposite magnets has been investigated by employing both the positron lifetime spectroscopy and the two-detector Doppler broadening measurements of the positron–electron annihilation γ quanta. Positron lifetime studies show that there are two kinds of interface structures in the magnets. One characterized by a positron lifetime of 155 ps is determined to be the interfacial amorphous layer. The other has a slack atomic structure in which structural free volumes, which were detected to be predominantly surrounded by nonmagnetic atoms Nd and B by the Doppler broadening measurements, have a larger size than that of one to two lattice vacancies of Fe. This is believed to weaken the magnetic exchange coupling between α-Fe and Nd2Fe14B grains in the nanocomposites. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 80 (2002), S. 1960-1962 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Nanocomposite Sm2Co17–Cu particles have been fabricated by low energy comilling of mechanically alloyed Sm2Co17 particles with Cu nanoparticles. The x-ray diffraction analyses show that the diffraction crystallite size (DCS) of Sm2Co17 decreases with increasing comilling time. Scanning and transmission electron microscopy observation demonstrates that the particle size is in the range of the DCS and the Sm2Co17 particles are separated by Cu particles. The coercivity as well as the remanence ratio decreases with increasing milling time due to the grain size reduction and grain separation. The nanocomposite Sm2Co17–Cu exhibits suitable magnetic and microstructure properties for high-density recording. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 80 (2002), S. 1028-1030 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Enhanced saturation magnetization was observed in granular nanostructured Ni/[Cu(II)–O–C] films deposited by the nonaqueous, electroless polyol process. The saturation magnetization of Ni–Cu complex films at room temperature was 112 emu/g, which was about two times that of bulk Ni (54.4 emu/g). It is suggested that the enhancement was caused by the magnetic interaction between the Ni particles and the amorphous Cu(II) complex. The observed shifted Curie temperature, large anisotropy field, and strong temperature dependence of saturation magnetization support this argument. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 80 (2002), S. 2973-2975 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: To understand and improve the applications of titanium-oxide nanoparticles, it is extremely important to perform a detailed investigation of the surface and the interior structural properties of nanocrystalline materials, such as rutile and anatase with diameter of few nanometers. Here, x-ray absorption spectroscopy has been used to identify the local Ti environment and characterize the related electronic structure. We combine experimental results at the Ti K edge in both bulk and nanocrystal samples to determine the lattice distortion via the characteristic pre-edge features and the variation in the multiple-scattering region of the x-ray absorption near-edge structure spectra. The correlation between peak intensities and surface-to-volume ratio of nanoparticles is also discussed. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 80 (2002), S. 485-487 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Nanometer-scale InGaN self-assembled quantum dots have been formed in an InGaN single-quantum-well structure on a (0001) sapphire substrate with In as the antisurfactant using low-pressure metalorganic chemical-vapor deposition. High-resolution transmission electron microscopy reveals that the average dimensions of InGaN nanometer-scale structures are as small as 4 nm wide and 1.5 nm high. Strong photoluminescence emission of the InGaN quantum dots was observed at room temperature with an emission peak of about 2.56 eV (485 nm) and a full width at half maximum of about 150 meV (30 nm). The choice of In as the antisurfactant also avoids the incorporation of foreign atoms in the active layers. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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