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  • 1995-1999  (5)
  • Polymer and Materials Science  (5)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 246 (1997), S. 23-48 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Ein 4,4′-Bis(maleimido)diphenylmethan-Harz wurde durch Addition von thermoplastischem Poly(etherimid) (PEI) Ultem 1000 modifiziert. Ein zweites System bestand aus einem Bismaleimid-Harz vom Typ Kerimid FE 70026 und einem Butadien-Acrylnitril-Copolymeren mit Maleinimid-Endgruppen (ITBN) als Modifizierungsmittel. Die kinetischen Parameter des Aushärtungsvorganges der Blendmatrix mit bzw. ohne Modifizierungsmittel wurden bei unterschiedlichen Temperaturen mit FTIR-Spektroskopie untersucht. Ein merklicher Anstieg der die Härtung beschreibenden Parameter Kc und Gc wurde bei beiden Systemen beobachtet. Morphologische Analysen des thermoplastisch modifizierten Harzes zeigten eine vollständige Phasenseparation und eine komplexe Morphologie, während im Falle der Modifizierung mit ITBN ein homogenes, einphasiges System erhalten wurde.
    Notes: A 4,4′-bis(maleimido)diphenylmethane resin was modified by adding a thermoplastic poly(ether imide) commercially available as Ultem 1000. A second system investigated was formed by a Kerimid resin and a maleimido-terminated butadiene-acrylonitrile copolymer (ITBN). For this system the kinetics of the curing process of the blend matrix with and without the rubber modifier was investigated at different temperatures by FTIR spectroscopy.A marked increase of the toughness parameters Kc and Gc was found for both the investigated systems. However, morphological analysis showed a complete phase separation and a complex morphology for the thermoplastic modified resin, while a homogeneous, single-phase system was obtained after rubber modification by ITBN.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 33 (1995), S. 1723-1730 
    ISSN: 0887-6266
    Keywords: high density polyethylene ; hydrogenated oligo(cyclopentadiene) ; blends ; phase structure ; stress-strain ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The influence of hydrogenated olio(cyclopentadiene) (HOCP) on tensile mechanical properties of its blends with high density polyethylene (HDPE) has been studied at 20, 80, and 100°C. The nominal stress-strain curves performed at 20°C indicate an increase of the modulus and a conspicuous decrease of the ultimate properties increasing the HOCP content in the blend. Blends with HOCP content 〉 20%-wt are found to be very fragile at 20°C. These behaviors have been related to the presence of the HOCP-rich phase that has the glass transition at about 55°C. At 20°C the HOCP oligomers act as a hardener for the HDPE. The nominal stress-strain curves performed at 80 and 100°C show a strong decrease of the modulus (compared to the value at 20°C), plastic deformation for all the blends tested, and rupture of HDPE and blend samples at the beginning of the cold-drawing. Moreover, the modulus and the ultimate parameters are found to decrease with the composition. The behaviors at 80 and 100°C have been related to several factors: the higher mobility of HDPE molecules at these temperatures compared to that at 20°C; the HOCP-rich phase that is at temperatures higher than its glass transition, and so it acts as a plasticizer for the HDPE; and the decreases of crystallinity and number of entanglements when the HOCP is added to the HDPE component. ©1995 John Wiley & Sons, Inc.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 55 (1995), S. 57-67 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Influence of spinning velocities on the mechanical and structural properties of polyethylene terephthalate (PET)/nylon 6 blend fibers have been reported. Fibers of PET/nylon 6 containing a small percentage of nylon (5% by weight) have been melt-spun at 3 different spinning velocities (2,900; 3,200; 3,600 m/min). The fibers have been characterized by thermal, morphological, structrual, and mechanical analysis. Various techniques such as SEM, DSC, X-ray diffraction, hot water shrinkage (HWS), viscosity, and birefringence have been used. SEM analysis revealed that in the blend, nylon 6 is well-dispersed as spheres in the PET matrix. The blend shows a marked decrease in the melt-flow index, which in turn leads to a beneficial effect on the rheological properties of the PET without negatively influencing its mechanical characteristics. This finding results in a saving on energetical requirements of the processing, as both temperature and pressure of spinning can be decreased. © 1995 John Wiley & Sons, Inc.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 58 (1995), S. 1825-1837 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A polyisobutene rubber was modified by grafting succinic anhydride onto its end groups and has been used as a toughening agent for an unsaturated polyester resin. Both the functionalization and the successive reaction between the modified rubber and the polyester was investigated by Fourier transform infrared spectroscopy (FTIR). The yield behavior of the cured resins was studied by compression measurements, while the fracture properties were determined at low and high strain rate. A morphological analysis of the investigated blends has been carried out by scanning electron microscopy (SEM). A considerable enhancement of tougheness has been achieved when the modified rubber was used in place of the plain polyisobutene. The effect was found to depend on the grafting degree of the rubber and on the time period during which the two-component mixture was allowed to react prior to the curing process. © 1995 John Wiley & Sons, Inc.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 62 (1996), S. 2107-2119 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An amino-terminated butadiene-acrylonitrile copolymer was chemically modified into a maleim-ido-terminated rubber and was used as a toughening agent for an unsaturated polyester resin. The reactive rubber was characterized by Fourier transform infrared spectroscopy. The mechanical and fracture properties of the blends containing the unmodified and the modified rubbers were investigated. Furthermore, a morphological analysis was carried out by scanning and transmission electron microscopy. A substantial enhancement of toughness was found when the modified rubber was used in place of the plain copolymer. © 1996 John Wiley & Sons, Inc.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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