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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 101 (1994), S. 3520-3523 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Electron spectroscopy has been carried out to investigate spectator and participant resonance Auger decay processes following the B 1s→2a2‘ excitation in gaseous BF3 molecules using monochromatized synchrotron radiation. The resonance-enhanced satellite bands corresponding to the spectator Auger electron emission form six broad peaks showing good correspondence with the normal Auger bands. Resonance enhancement of the photolines corresponding to the participant Auger electron emission occurs only for the bonding orbitals having B character.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Langmuir 5 (1989), S. 1326-1331 
    ISSN: 1520-5827
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 63 (1992), S. 1690-1694 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: We have developed a method for determining metal-atom number-density integrated over a line-of-sight (i.e., the column density) by measuring the optical depth in the wings of the pressure-broadened resonance lines. This method is capable of monitoring the column density in situ during photoelectric absorption measurement of metal vapors in a synchrotron radiation beamline. The present method requires measuring the reduced absorption coefficients of the metal–metal and metal–buffer-gas collisional quasimolecules γMM and γMG and the effective vapor length l before its use. We thus describe also the procedure for obtaining γMM, γMG, and l using He-buffered Yb vapor as a specific example.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 94 (1991), S. 1907-1912 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Reduced absorption coefficients γBaBa were measured for the far-wing absorption of the self-broadened Ba6s2 1S0–5d6p 1P1 line, Ba(6s2 1S0) +Ba(6s2 1S0)+(h-dash-bar)ω → Ba*(5d6p 1P1)+Ba(6s21 S0)and the pair absorption Ba(6s2 1S0)+Ba(6s2 1 S0) +(h-dash-bar)ω→Ba*(6s6p 1P1 +Ba*(6s5d 1D2). The self-broadening shows the red-shaded asymmetric profile: γBaBa on the red wing is proportional to Δν−3/2, where Δν is the detuning from the line center. The pair absorption shows a broad asymmetric peak having a blue tail and a blue satellite. The estimated γBaBa, which is based on the quasistatic line-broadening theory and the long-range dipole–dipole interaction between the relevant atomic excited levels, shows reasonable agreement for the red wing of the self-absorption whereas it gives larger values by a factor of 3 for the blue tail of the main peak for the pair absorption.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 94 (1991), S. 1903-1906 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have determined reduced absorption coefficients on far wings of the Ba 6s2 1S0–5d6p 1P1 line broadened by He, Ne, Ar, Kr, and Xe. Using the unified Franck–Condon theory, we analyzed the blue satellite band observed for each of the He, Ne, and Ar perturbers and obtained the position and the height of the extremum of the difference potential-energy curve to be 6.5±1.5 A and 251±4 cm−1 for He, 7.6±2 A and 114±2 cm−1 for Ne, and 7.4±2 A and 70±2 cm−1 for Ar. We have also observed the collision-induced–dipole absorption bands associated with the Ba 6s2 1S0–6s7s 1S0 forbidden transition for all rare-gas perturbers.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 4495-4498 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Reduced absorption coefficients have been measured for the collision-induced-dipole (CID) absorption bands associated with the 5s–4d transition of atomic strontium perturbed by He, Ne, Ar, Kr, Xe, and Sr. The main CID absorption band, assigned to 5sΣ–4dΣ, extends from the position of the atomic 5s–4d transition towards the shorter-wavelength side for every perturber. For Xe and Kr, an additional small absorption band is seen at the foot of the atomic 5s–4d transition. The former 5sΣ–4dΣ band is interpreted to result from collisional mixing of the 5p state of atomic Sr into the molecular 4dΣ state for small internuclear separations, while the latter band is interpreted to result from the collisional quadrupole (strontium)–dipole (Xe or Kr) interaction.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 9492-9493 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 95 (1991), S. 8083-8088 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have determined reduced absorption coefficients in far wings of the Yb (6s2)1S0–(6s6p)1P1 line broadened by He, Ne, Ar, Kr, Xe, and Yb. We find a prominent blue-satellite peak for all perturbers and undulations between the satellite peak and the line center for Ne, Ar, Kr, and Xe. Analyzing the satellite band with the aid of the unified Franck–Condon method, we obtain the position and the height of the extremum on the difference potential-energy curves concerned. We have also observed collision-induced-dipole absorption bands associated with the transition (6s2)1S0–(6s5d)3D2 of atomic Yb for Ne, Ar, Kr, and Xe perturbers.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 4499-4503 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have observed many collision-induced-dipole (CID) absorption bands arising from the transitions between quasimolecular ground and high-lying (n≤10) states in the strontium–rare-gas systems. For each absorption band, we have measured the energy shift of the absorption peak from the energy of the correlating atomic forbidden transition and the effective oscillator strength per unit perturber density fCID/Np. The shift is roughly proportional to the electron scattering length L0 for each rare-gas atom, whereas the fCID/Np is roughly proportional to L20. The shift decreases in general as the principal quantum number n increases, and increases as one goes from the s state to the d state, and to the degenerate manifold state with l≥3. These general features of the shift and fCID/Np are consistent with the predictions by a simple Fermi-potential model, suggesting the important role of the interaction between a Rydberg electron and a rare-gas atom in the CID absorption processes.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: To assess the ability of the high-speed K-edge energy subtraction system which was made at beamline 8C of Photon Factory, Tsukuba, we performed an animal experiment. Rabbits were used for the intravenous K-edge subtraction angiography. In this paper, the actual images of the artery obtained by this system, are demonstrated. The high-speed K-edge subtraction system consisted of movable silicon (111) monocrystals, II–ITV, and digital memory system. Image processing was performed by 68000-IP computer. The monochromatic x-ray beam size was 50×60 mm. Photon energy above and below iodine K edge was changed within 16 ms and 32 frames of images were obtained sequentially. The rabbits were anaesthetized by phenobarbital and a 5F catheter was inserted into inferior vena cava via the femoral vein. 1.5 ml/kg of contrast material (Conlaxin H) was injected at the rate of 0.5 ml/kg/s. TV images were obtained 3 s after the starting point of injection. By using this system, the clear K-edge subtracted images were obtained sequentially as a conventional DSA system. The quality of the images were better than that obtained by DSA. The dynamical blood flow was analyzed, and the best arterial image could be selected from the sequential images. The structures of aortic arch, common carotid arteries, right subclavian artery, and internal thoracic artery were obtained at the chest. Both common carotid arteries and vertebral arteries were recorded at the neck. The diameter of about 0.3–0.4 mm artery could be clearly revealed. The high-speed K-edge subtraction system demonstrates the very sharp arterial images clearly and dynamically.
    Type of Medium: Electronic Resource
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