ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The A˜ 2Δ–X˜ 2Π electronic transition of the CCN free radical was observed in emission with a high-resolution Fourier transform spectrometer. The CCN was jet-cooled in a corona-excited supersonic jet expansion of diazoacetonitrile (HC(N2)CN) in helium. From the 000–000, 000–001, 000–002, and 000–100 vibronic bands spectroscopic constants were derived including the ground-state vibrational frequencies, ν3=1050.7636(6), 2ν3=2094.8157(18), and ν1=1923.2547(69) cm−1.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.458016
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