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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 24 (1993), S. 131-141 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Arc-PVD-Coating of Cemented Carbides and Analysis of their Functional Behaviour in Interrupted Cut MachiningInterrupted machining of quenched and tempered steel demands the application of tools with high resistance against mechanically and tribologically induced wear. These demands can not be fully satisfied by uncoated carbides. Also CVD-coatings give only some improvement due to a certain embrittlement of the substrate during the coating process. PVD-coatings deposited at low temperatures without affection of the substrate lower the influence of the relevant wear mechanisms preferably at moderate cutting speeds.The combination of tough substrates with structural and compositional optimized coatings results in a multiplication of tool life within the whole range of low and medium cutting speeds. Coatings with homogenious structure, compressive residual stresses and high content of metalloides ensure excellent resistance against wear.Titanium-carbonitride deposited on carbide was found to be superiour compared with other carbonitride, nitride and carbide coatings within the system Ti—Zr—C—N due to excellent tribological properties. It was optimal suited for the interrupted cut application.
    Notes: Die Zerspanung von höherfesten Stahlwerkstoffen in unterbrochenen Schnitten stellt an die Werkzeuge hohe mechanische und tribologische Anforderungen, denen unbeschichtete Hartmetalle in vielen Fällen nicht gerecht werden können. Während sich bei der Zerspanung von höherfestem Stahl in stark unterbrochenen Schnitten durch die CVD-Beschichtung von Hartmetallen auf-grund prozeßbedingter Versprödungseffekte kaum Leistungssteigerungen erzielen lassen, können PVD-Hartstoffbeschichtungen, die bei substratschonend niedrigen Prozeßtemperaturen abgeschieden werden, dem Auftreten der relevanten Schädigungsmechanismen besonders bei niedrigen und mittleren Schnittgeschwindigkeiten entscheidend entgegenwirken.Insbesondere mit zähen Substratsorten sowie mit strukturell und kompositionell optimierten Schichten können Standzeitvervielfachungen im gesamten unteren und mittleren Schnittgeschwindigkeitsbereich erzielt werden. Homogene Schichtstrukturen, hohe Druckeigenspannungen und hohe Metalloidgehalte der Hartstoff-schichten gewährleisten eine hohe Verschleißfestigkeit. Titankarbonitrid zeichnet sich auf Hartmetallen gegenüber anderen karbonitridischen, nitridischen und karbidischen Schichten des Systems Ti—Zr—C—N durch ein besonders günstiges tribologisches Verhalten aus und hat sich als optimaler Beschichtungswerkstoff für unterbrochene Schnitte erwiesen.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 1 (1978), S. 69-71 
    ISSN: 0935-6304
    Keywords: Gas Chromatography Mass Spectrometry ; Capillary, glass/Varian, MAT 311A ; Separation and detection (El, Cl) of some roast coffee constituents ; Three new phenolic compounds found ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A roast coffee infusion (nicaragua arabica) was acidified (pH 1,5) with hydrochloric acid and extracted with diethyl ether in a perforator. After evaporation of the solvent the residue was treated with N-methyl-N-trimethylsilyl trifluoroacetamide and analyzed by glass capillary GC/MS. The main components were identified by their electron impact and isobutane chemical ionization mass spectra. 1,2,4-trihydroxy benzene, 1-ethyl-3, 4-dihydroxy benzene and 2,3-dihydroxy toluene were identified as new constituents of roast coffee with possible emetic properties.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 2 (1979), S. 378-384 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary, glass ; Glass capillaries for low volatile polar natural products analysis ; Application to N-TFA-dipeptide, TMS-ribose, TMS-manno-samin, peptide sequence analysis ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Two published procedures for glass capillary column production are applied to produce capillaries for chromatography of polar natural compounds. Soda lime glass capillaries, after leaching with aqueous HCL, are either treated with colloidal silicic acid or with barium carbonate and coated with either Silar 7CP or SE 52. A test mixture as well as polar carbohydrate and peptide mixtures are chromatographed on the different columns and their chromatographic properties are evaluated. Combined capillary gas chromatography-electron impact and chemical ionization mass spectrometry are used for identification of the peptide sequence.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 90 (1978), S. 147-147 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1976), S. 241-244 
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The reaction products of trifluoroacetic anhydride with peptide amides are identified as stable heterocyclic imidazolin-5(4)-ones, which can be analysed by gas chromatography mass spectrometry. The mass spectra show intense molecular ions and allow the assignment of the amino acid sequence.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 60 (1977), S. 2071-2078 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Metabolites from Microorganisms, 6-Chlorogenistein and 6,3′-DichlorogenisteinA strain of Streptomyces griseus produced chlorinated metabolites in media containing soybean meal. Two of these metabolites were isolated together with a chlorine free compound which could be identified as the isoflavone genistein (I) by its spectral properties and by comparison with an authentic sample. By NMR. and mass spectroscopy the chlorinated compounds were shown to be 6-chlorogenistein (II) and 6,3′-dichlorogenistein (III).The 7-glucoside of genistein is a constituent of soybean meal; it is hydrolysed and chlorinated by Streptomyces griseus.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 17 (1978), S. 140-140 
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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