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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 66 (1962), S. 557-559 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 27 (1955), S. 1306-1307 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 62 (1958), S. 372-373 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 61 (1957), S. 1314-1318 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 1372-1385 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The heat capacity of CH3D on graphite has been measured at low temperatures (0.3–7 K) and shown to have a Schottky anomaly resulting from the difference in energy between states with the single deuterium atom pointing away from the surface (D up) and states where the deuterium atom is part of the tripod of atoms pointing towards the surface (D down). The energy difference is 380±20 μeV with the D-down configuration being the more stable. Incoherent neutron scattering spectra of CH3D adsorbed on exfoliated graphite have been used to resolve the finer detail of the tunneling splittings in the system. The energy levels can be described quantitatively in terms of five parameters, the splitting between D-up and D-down configurations and two pairs of parameters, one pair related to the rotational potential about the unique C–H(D) bond normal to the surface and the other pair to rotation about one of the three equivalent C–H(D) bonds pointing towards the surface. Comparison of the results from CH3D and earlier results from CH4 show that both potentials contain two Fourier components, approximately 75% of a threefold and 25% of a sixfold component in phase with one another. The values originally obtained from the CH4 tunneling spectrum for the two barrier heights 202 and 172 cm−1 for rotation about the unique and nonunique axes, respectively, are shown to have an uncertainty of about 5% resulting from the approximations used for the shape of the potential in the interpretation of the earlier experiment.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 11 (1993), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract ‘Peak’metamorphic carbon isotope fractionations between calcite and graphite (ΔCal–Gr) in marbles and calc-silicates from the Cucamonga granulite terrane (San Gabriel Mountains, California) range from 3.48 to 2.90%. The data are used to test three previously published calibrations of the calcite–graphite carbon isotope thermometer. An empirical calibration of the calcite–graphite carbon isotope thermometer gives temperatures of 700–750°C; a theoretical–experimental calibration of the system gives temperatures of 760°–870°C; an experimental calibration gives temperatures of 870–1300°C. Temperatures calculated using the empirical calibration are in agreement with those calculated from garnet-based cation exchange thermometry when uncertainty is considered. Temperatures calculated using the theoretical–experimental calibration overlap the upper range of cation exchange thermometry temperatures and range to 50°C higher. The experimental calibration yields temperatures from 50 to 480°C higher than those from cation exchange thermometry. Moreover, temperatures from the experimental calibration are also inconsistent with mineral and melt equilibria in the granulite phase assemblage.Despite the better agreement between cation exchange thermometry and the empirical calibration of the calcite–graphite system, temperatures calculated using the theoretical–experimental calibration may be real peak metamorphic temperatures. If retrograde diffusion partially reset garnet-based cation exchange thermometers by c. 50°C, then the cation exchange temperatures are consistent with those from the theoretical–empirical calibration. Thermometric evidence from biotite dehydration melting equilibria is consistent with either the empirical calibration if melting was fluid-present, or the theoretical–experimental calibration if melting was fluid-absent.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Structures in rocks altered by the infiltration of magmatic fluids provide key constraints on the relative timing of plutonism and regional deformation in the central Old Woman Mountains, south-eastern California. In this well-exposed area the Scanlon shear zone, a belt of attenuated, shallowly dipping, amphibolite facies Palaeozoic strata, is in contact with two tabular, Late Cretaceous (∼74 Ma) granitoid plutons. The shear zone contains massive wollastonite-bearing skarns ∼40 m above the contact with the Old Woman granodiorite. Field evidence, petrological data and stable isotope compositions indicate that the mineral assemblages in these skarns formed when the granodiorite crystallized and exsolved water-rich, magmatic fluids. Structural features in the skarns, which include transposed wollastonite foliations, syntectonic vesuvianite and garnet porphyroblasts, and quartz ± wollastonite veins, afford an opportunity to monitor the regional strain at the time of pluton crystallization. These structures yield a broad range of timing relationships that indicate synkinematic mineral growth with deformation ending first, at c. 74 Ma. The metasomatic structures are kinematically compatible with the regional deformation observed in other lithologies and no post-tectonic features overprint the fabrics in the skarns. Observations of isoclinally folded and boudinaged dykes and pegmatites, granodiorite saddle reefs in isoclinal fold hinges, and undeformed, locally pegmatitic dykes also yield a broad range of timing relationships indicative of synkinematic plutonism, with deformation ending first. Our results show that coupling petrological and stable isotope data with structural analysis is effective for unravelling the relative timing of heat and mass transfer processes in pluton-wallrock systems.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Oxygen isotope ratios, whole rock major and trace element compositions, and petrological characteristics of 52 samples from nine distinct igneous lithologies in the lower plate of the Whipple Mountain metamorphic core complex of south-eastern California indicate that both mylonitic and non-mylonitic lithologies underwent exchange with surface-derived meteoric waters. Broadly granodioritic lithologies are characterized by whole rock δ18O values that range from 10.6 to 2.6‰. Isotopic compositions of quartz and feldspar mineral separates indicate that quartz has largely retained original igneous compositions but that feldspar has undergone variable and often large 18O-depletions (up to 6.5‰).Over 4 km of structural relief is exposed in lower plate gneisses below the Whipple detachment fault including non-mylonitic lithologies at shallow structural levels above the mylonite front, and mylonitic gneisses at intermediate to deep levels below the mylonite front. Coupled δ18Oqtz - δ18OFsp systematics of non-mylonitic and mylonitic andesite to rhyolite dykes from shallow and intermediate structural levels of the lower plate document two episodes of hydrothermal alteration: a high-temperature (〉c.600d̀C) episode involving a metamorphic or magmatic fluid with δ18O values ∼ 7‰ and a low-temperature (c.350d̀C) episode involving low-δ18O meteoric fluids. All the dykes that document exchange with meteoric fluids are non-mylonitic. Coupled δ18OFsp systematics of non-mylonitic and mylonitic granodioritic gneisses from above and below the mylonite front also document low-temperature (c. 350d̀ C) exchange with meteoric fluids. The data indicate that infiltration of meteoric fluids occurred as lower plate lithologies were juxtaposed against the base of the faulted upper plate. High-angle normal faults in the upper plate served as the conduits for the downward circulation of surface-derived fluids. Meteoric fluids were able to penetrate across the detachment fault into the lower plate.Uplift rates coupled with independent cooling rates indicate that surface-derived fluids penetrated to a depth of c.4km and possibly as deep as c.8km. Penetration of surface-derived fluid into the ductile deformation regime is not required to explain the low δ18O values observed in lower plate lithologies of the Whipple Mountain metamorphic core complex.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Grass and forage science 18 (1963), S. 0 
    ISSN: 1365-2494
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Three trials were carried out to compare the feeding value of silage and barn-dried hay for fattening bullocks of approximately 8 cwt initial body weight. In each case the silage and hay were cut from the same sward at the same time. In the first trial the bullocks fed on hay gained 1·88 lb/day while those self-fed on silage gained 1·55 lb/day during a 70-day feeding period. In the second trial of 70 days, the bullocks fed on hay gained 1·96 lb/day and those fed on silage from a trough gained 2·39 lb/day. In the third trial, individually-fed bullocks housed in stalls and given the same hay and silage as used in Trial 2 gained 123 lb/day on hay and 127 lb/day on silage. The significance of these results is discussed in relation to the findings of other workers.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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